Illustrated Physics
physics, drawn
Concept

Mean-field theory — where it appears

An approximation that replaces the interactions a particle has with its neighbours by the average field they all produce. It is often accurate in dense, weakly coupled systems and fails where a single neighbour matters, as with strongly correlated ions or near a critical point.

Named by 5 essays across 3 fields — each of them below, with the objects they name alongside it.

The interaction that orders a magnet is not the magnetic one. For six ordered magnets, two temperatures on a logarithmic scale: the energy of the magnetic interaction between two neighbouring moments, expressed as a temperature, and the temperature at which the material actually orders. iron orders at 1043 K against a dipolar scale of 0.201 K, a factor of 5182; cobalt orders at 1394 K against a dipolar scale of 0.117 K, a factor of 11961; nickel orders at 627 K against a dipolar scale of 0.015 K, a factor of 42312; gadolinium orders at 293 K against a dipolar scale of 0.790 K, a factor of 371; europium oxide orders at 69 K against a dipolar scale of 0.615 K, a factor of 112; lithium holmium fluoride orders at 1.53 K against a dipolar scale of 1.230 K, a factor of 1.24. The five ferromagnets order between a hundred and forty thousand times above the only interaction their moments have with each other, so whatever aligns them is not magnetism. The sixth is the control: lithium holmium fluoride is a magnet whose ordering really is dipolar, and its two temperatures agree.

What holds a magnet together is not magnetism

Two neighbouring moments in iron interact magnetically with an energy worth a fifth of a kelvin, and iron keeps its order to 1,043 kelvin. Whatever aligns them is five thousand times stronger than the only force they exert on one another — and it is electrostatic, with the exclusion principle deciding which of two spatial arrangements two electrons may use.

electromagnetism · Magnetisation Mean field always pushes; correlations pull. The pressure between two planes of equal charge with only their own counterions between them, against their separation, in units of the Gouy–Chapman length μ for the separation and 2πℓ_Bσ²kT for the pressure. The upper curve is the Poisson–Boltzmann result, solved from k·tan(kd/2) = 1: it is the density of counterions at the midplane and is positive at every separation, falling from the ideal-gas 2/d at contact to π²/d² far apart — 1.71 at 1μ, 0.290 at 4μ. The lower curve is the strong-coupling limit, 2/d − 1, which the same ions reach when their valence and the surface charge are high. It crosses zero at d = 2μ and is negative beyond, tending to −1: the two like-charged planes attract, and the separation 2μ is where they come to rest.

The like charges that pull together

Two surfaces carrying the same charge, with nothing between them but the ions that neutralise them, ought to repel, and the standard mean-field theory proves that they always do. With calcium or spermine as the counterions they attract, and come to rest a fraction of a nanometre apart. The mean field misses it because it averages the ions into a smooth cloud, and multivalent ions are too strongly repelled by each other to form one. Each keeps a patch of surface to itself, and the pressure between the plates becomes a single ion's business.

fluids · Osmosis Chains counted, and then blobs. The osmotic pressure of a polymer solution in a good solvent against concentration, on logarithmic axes, for chains of 1,000, 10,000, 100,000 segments. Dilute, each chain is one particle and the pressure is van 't Hoff's, proportional to the number of chains: a line of slope one, lower for longer chains by the ratio of their lengths. Past the overlap concentration of each, marked, the coils interpenetrate and the curves bend up onto a single line of slope 2.31 that does not depend on chain length at all. The overlap concentration falls as the chains lengthen, by a factor of 5.8 for each tenfold increase in length, which is why the longest chains leave the counting of molecules first.

The pressure that stops counting molecules

Van 't Hoff's law counts dissolved particles, and for a dilute polymer each chain is one particle, however many thousand segments it has. That is how osmometers weigh polymers. Concentrate the solution until the coils overlap and the count changes. The pressure stops depending on how long the chains are and grows as the 2.3 power of the concentration, the same for chains a thousand segments long and a hundred thousand. The unit being counted is no longer a molecule. It is a stretch of chain as long as the mesh of its neighbours allows, and it has no chemical identity at all.

fluids · Osmosis The ring where an axisymmetric field vanishes. Field lines of the slowest-decaying dipole field of a conducting sphere, drawn in a plane through its axis (the axis is the left edge, the sphere's surface the arc). Each line is a contour of the flux function, which is zero on the axis and at infinity and positive between, so it must have a maximum. Here the maximum is on the equator at 0.873 of the radius: there the lines shrink to a point, which in three dimensions is a ring round the axis on which the meridional field is exactly zero. 7 of the 11 drawn lines leave the sphere and close outside; the other 4 close inside, round the ring. The toroidal current that makes the field is not zero on the ring: it is 89 per cent of its largest value.

The field no symmetric flow can keep

The Earth's core would forget its magnetic field in about forty thousand years, and the field is at least three and a half thousand million years old, so something must be making it again all the time. The obvious candidate is the flow of liquid iron. In 1934 Thomas Cowling proved that the simplest version cannot work: no motion of a conductor, however fast or however arranged, can keep up a field that is symmetric about an axis. The reason is a single ring inside the field where the current it needs cannot be driven.

astrophysics · Flux freezing Water's surface tension, all the way to the critical point. The surface tension of water against its liquid vapour, from the international standard correlation, against temperature from 0 °C to the critical point at 373.946 °C. 20 °C: 72.7 mN/m; 100 °C: 58.9 mN/m; 200 °C: 37.7 mN/m; 300 °C: 14.4 mN/m; 370 °C: 0.4 mN/m. It falls almost in a straight line for most of the range and then bends down to reach zero exactly at the critical point, where liquid and vapour stop being two things. The bend is a power law, the gap to the critical temperature raised to 1.256.

The tension that vanishes where the phases meet

Surface tension is usually treated as a property of a liquid, like its density. It is a property of a boundary between two things, and it can only exist while there are two things. Heat water in a sealed tube and its surface tension falls steadily, then faster, and reaches exactly zero at 374 °C, where liquid and vapour stop being different. On the way the surface stops being a surface: the step in density spreads from a molecule's width to thousands, and the rate at which the tension dies turns out to be a number the whole family of critical points shares and the simplest theory gets wrong.

fluids · Surface tension

Named alongside it

The objects these essays reach for when they reach for this one.

Correlation lengthOsmotic pressureBjerrum lengthConductivityContact value theoremCorrelationCounterion condensationCoupling parameterCritical exponentCritical pointCurie temperatureDipole dipole interaction

All concepts