Coupling parameter — where it appears
Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.
The like charges that pull together
Two surfaces carrying the same charge, with nothing between them but the ions that neutralise them, ought to repel, and the standard mean-field theory proves that they always do. With calcium or spermine as the counterions they attract, and come to rest a fraction of a nanometre apart. The mean field misses it because it averages the ions into a smooth cloud, and multivalent ions are too strongly repelled by each other to form one. Each keeps a patch of surface to itself, and the pressure between the plates becomes a single ion's business.
The dust a plasma freezes into a crystal
Sprinkle microscopic plastic spheres into a glowing discharge and each one charges itself to tens of thousands of electrons, because the plasma's light, fast electrons reach it far more often than its heavy ions. The charge holds the grains up against gravity in the sheath above the electrode, and it makes their mutual repulsion so strong compared with their jiggling that, at room temperature, they freeze into a hexagonal crystal with a lattice spacing a camera can resolve. A plasma, the hottest and most disordered state of matter, is where the most strongly ordered one was found to form most easily.
Named alongside it
The objects these essays reach for when they reach for this one.
Bjerrum lengthContact value theoremCorrelationCounterion condensationCrystal latticeDebye lengthElectrostaticsFloating potentialLike charge attractionMean-field theoryOsmotic pressurePhase transition