Illustrated Physics
physics, drawn
Concept

Heat engines — where it appears

Machines that take heat from a hot body, give some to a cold one and deliver the difference as work. Carnot's argument bounds every one of them by a ratio of two temperatures, with nothing about the fuel, the working substance or the design entering the bound at all.

Named by 3 essays across one field — each of them below, with the objects they name alongside it.

The ceiling, the estimate, and three power stations. Two efficiencies against the ratio of the cold reservoir's temperature to the hot one. The upper curve is Carnot's 1 − Tc/Th, which is a ceiling on the work per unit of heat and is reached only by an engine that runs infinitely slowly, because a reversible heat flow needs a vanishing temperature difference to drive it and therefore infinite time. The lower curve is 1 − √(Tc/Th), the efficiency of an engine with finite thermal contact run for the most power rather than the most work. Three measured plants are marked: West Thurrock, coal runs at 36 per cent against a ceiling of 64 and a finite-time estimate of 40; CANDU, nuclear runs at 30 per cent against a ceiling of 48 and a finite-time estimate of 28; Larderello, geothermal runs at 16 per cent against a ceiling of 33 and a finite-time estimate of 18. Every one of them is closer to the lower curve — within 4.4 points at worst, against 16.5 at best from the ceiling. The second law is not what limits a working power station. What limits it is that somebody wants the electricity this year.

The engine that has to finish

Carnot's ceiling is exact and it is reached only by an engine that takes for ever, because a reversible heat flow needs a vanishing temperature difference to drive it. Ask instead for the most power rather than the most work per joule of heat, and the answer is a different function of the same two temperatures — and three measured power stations sit on it rather than on the ceiling.

thermodynamics · Heat engines A fridge with no work going into it, and its ceiling. How much heat a three-reservoir machine can lift out of a cold space per unit of heat supplied to drive it, against the temperature of the driving heat, for 3 cold temperatures and an ambient of 300 kelvin. No work enters or leaves: the machine takes heat in at the top, takes heat in at the bottom, and rejects the sum at ambient. That it can do anything at all is the surprise — the second law allows heat to be moved up a gradient provided a larger flow is moved down one, and the accounting is a single inequality in the three entropy flows. The ceiling is the product of two familiar expressions, and at 450 kelvin driving a 253-kelvin space it is 1.79. The marks are what real machines achieve, which is a fifth to a third of it — absorption refrigeration is not efficient and is chosen when the heat is free and the silence and the absence of moving parts are worth something.

A fridge with no work going into it

Every engine here so far turns heat into work or work into a heat flow. A machine exchanging heat with three reservoirs and doing no work at all can still move heat from cold to hot, and the ceiling on how much is the product of two Carnot expressions — an engine's efficiency times a fridge's coefficient of performance. A gas flame makes ice, and the accounting is one inequality in three entropy flows.

thermodynamics · Heat engines One dimensionless group between an engine and Carnot. The efficiency of a thermoelectric couple against the temperature of its hot side, with the cold side at 300 kelvin, for 4 values of the figure of merit, and the Carnot ceiling drawn above them. The expression has exactly one material quantity in it — the dimensionless group formed from the Seebeck coefficient squared, the electrical conductivity, the temperature and the thermal conductivity — and everything else is the two temperatures. At 600 kelvin, a figure of merit of one gives 10.8 per cent against a Carnot ceiling of 50.0, and a figure of merit of four gives 22.6. The approach to the ceiling is slow: every doubling of the group buys less than the last, so the difference between a good material and a perfect one is smaller than the difference between a poor material and a good one.

An engine with one number in it

A thermoelectric couple has no moving part and no working fluid, and its efficiency is the Carnot value multiplied by a factor containing exactly one dimensionless group of material properties. Sixty years of effort have moved that group from about one to about two, and the reason it is hard is that its three ingredients are not independent: raising the conductivity ruins the coefficient it is squared against, and the only lever that is really free is the heat the lattice carries.

thermodynamics · Heat engines

Named alongside it

The objects these essays reach for when they reach for this one.

Carnot efficiencyEntropyOptimisationThe second lawAvailable workThe Carnot cycleChemical potentialCoefficient of performanceConductivityDopingEfficiencyEndoreversible

All concepts