Concept

Diamagnetism — where it appears

The weak repulsion of a material from a magnetic field, arising because an applied field induces currents that oppose it. It is present in every substance and is usually swamped; a superconductor is the extreme case, expelling the field entirely rather than partially.

Named by 3 essays across one field — each of them below, with the objects they name alongside it.

The field a classical partition function cannot see. The momentum plane of one classical charge, in units of the root-mean-square thermal momentum. With no field the Boltzmann weight is a set of circles about the origin; with a field the same circles sit about p = qA, displaced and otherwise unaltered, because the energy depends on p only through p − qA. Integrating over the whole plane therefore cannot notice the displacement, and the numbers beside the drawing are that integral evaluated at 6 displacements: the largest departure from the zero-field value is 3.3e-16, which is the precision of the arithmetic and not a physical effect. The classical free energy has no B in it, so the classical magnetisation is exactly zero at every field and every temperature — no paramagnetism, no diamagnetism, no ferromagnetism. Every magnetic material is therefore evidence of something classical mechanics does not contain.

The magnetism classical physics forbids

Write down the partition function of any collection of classical charges in a magnetic field, and the field cancels out. Not approximately, not to leading order — the integral is over all of momentum space and the field only shifts where the middle of it is. So classical statistical mechanics predicts no paramagnetism, no diamagnetism and no ferromagnetism, and a compass needle is a quantum instrument.

electromagnetism · Magnetisation
Every stationary point has a way out. The potential along four lines through the most symmetric point of a symmetric arrangement of 4 equal charges at the corners of a square — the one place a trap might be expected. In the plane of the square the potential rises in every direction; out of the plane it falls. The point is stationary and it is a saddle, which is what Laplace's equation forces: the three second derivatives must sum to zero — computed here as 1.4e-5 against the individual values of order 2e+0 — so if two of them are positive the third must be negative. A particle released here rolls away along the direction that falls. No amount of ingenuity in placing the charges changes this, because the constraint is on the equation rather than on the arrangement, and it is why every real trap for a charged particle either uses time-varying fields, or a magnetic field with a velocity, or a material with a negative response.

Nothing can be held still by a static field

However many charges are arranged, however cleverly, a charge placed among them has somewhere to fall. The reason is one line of arithmetic — the potential in empty space satisfies Laplace's equation, and a solution of that equation has no interior maximum or minimum — and the consequence is that every real trap for a charged particle works by breaking one of the assumptions rather than by being cleverer.

electromagnetism · Potential
Circles that go nowhere, and a current across the line. Gyrating ions in a uniform magnetic field pointing out of the page, with 60 guiding centres drawn from a density that falls by a factor of e every 3 gyroradii to the right, and Maxwellian speeds. Every ion goes round clockwise and none of the circles moves. Of the circles that cross the dashed vertical line, those centred to its left cross it moving down and those centred to its right cross it moving up; in this sample 11 cross moving down and 7 moving up, a count a sample this small could turn either way. Because there are more circles on the left, the ions at the line move downwards on average over every speed and phase, at exactly the thermal speed squared over the gyrofrequency times L, 0.33 thermal speeds, computed by averaging over speeds and phases and checked against that value. It is a current, carried by circles whose centres are still.

The current no particle carries

A magnetised plasma holds its own pressure against the field only if a current flows across the pressure gradient, and the fluid equations say exactly how much. Follow the particles in a uniform field and none of them is going anywhere; every guiding centre is still. The current is real all the same. It is made of circles that are more crowded on one side of a line than the other, and when the field is not uniform, the drifts that do move the guiding centres flow the wrong way.

electromagnetism · Magnetism

Named alongside it

The objects these essays reach for when they reach for this one.

MagnetisationAngular momentumBohr magnetonThe Boltzmann factorDiamagnetic currentDriftEarnshaws theoremEquilibriumFree energyGuiding centreHarmonic functionIon trap

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