Concept

Coulomb force — where it appears

The inverse-square attraction or repulsion between two charges, with the constant fixed by the permittivity of the vacuum. Its exact inverse-square form is what gives atoms their extra conserved vector and hydrogen its accidental degeneracy.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

$The charge a plasma hides. The potential around a charge in a plasma, as a fraction of the bare Coulomb potential at the same distance, against distance measured in screening lengths. The electrons crowd toward the charge and the ions move away until the rearrangement cancels the field, and what is left falls as exp(−r/λ_D) on top of the ordinary 1/r. At one screening length the potential is already down to 37 per cent of the bare value, at three to 5 per cent, and at ten to 4 × 10⁻⁵ — so a charge in a plasma is invisible beyond a few λ_D, and the long range of the Coulomb force, which is what makes electrostatics awkward everywhere else, is simply gone. The screening length at 10¹¹ m⁻³ is 3.8 mm at 300 K, 6.9 mm at 1000 K, 21.8 mm at 10000 K, rising as the square root of the temperature because a hotter electron is harder to hold in place. Drawn this way the three curves coincide exactly: the shape is universal and the only thing a plasma's density and temperature decide is the length written on the axis.$

The long-range force that does not reach

The Coulomb force falls off as slowly as gravity does, which is what makes electrostatics awkward — every charge is in principle in contact with every other. Put the same charge into a plasma and it becomes invisible beyond a few millimetres, because the mobile charges around it rearrange until its field is cancelled. What is left is a screened potential with a definite range, and that range is what makes a plasma a plasma.

astrophysics · Plasma oscillation

Why it stops falling in. The energy of an electron confined to a region of radius r around a nucleus, as the sum of two terms with different powers: a confinement energy ħ²/2mr² that rises without limit as the region shrinks, and a Coulomb attraction −Ze²/4πε₀r that falls. At Z = 1 the sum is least at 52.92 pm, where it is -13.61 eV. Both numbers are found by searching the drawn curve and both agree with the Bohr radius over Z and minus Z² Rydbergs to a part in a million. Nothing was quantised to get them. The only quantum input is that confining an electron to a region costs kinetic energy, which is the uncertainty relation and nothing more.

Why an atom is the size it is

A tenth of a nanometre is not a measured constant of nature but the outcome of a competition: confining an electron costs kinetic energy, and the nucleus pays for confinement with attraction. Minimising the sum gives the number, and changing the masses moves it by four orders of magnitude.

quantum · Atomic structure

Fringes that identical nuclei add. The cross-section for two identical spinless nuclei repelling each other, divided by the classical answer — the Rutherford counts for the nucleus hit and the nucleus thrown, added — against the scattering angle in the centre-of-mass frame, for Sommerfeld parameters η = 1, 4 and 16 (η is half the closest approach in units of the wavelength over 2π). Because the detector cannot tell which nucleus it caught, the two amplitudes add before squaring, and the cross term oscillates in angle: at 90° the two paths are mirror images and the rate is exactly twice the classical one at every energy. Between 30° and 90° the curve completes about 2 oscillations for η = 4 and 7 for η = 16 — their number grows in proportion to η, which is to say in proportion to 1/ħ.

The scattering quantum mechanics returns unchanged

Rutherford worked out how alpha particles bounce off a nucleus by treating them as tiny planets on hyperbolic orbits, two years before Bohr's atom and fifteen before quantum mechanics. He had no right to be exactly correct, and he was: the full quantum calculation returns his formula without a single correction, at every energy. Coulomb's force is the one force for which that happens. Make the two nuclei identical, though, and quantum mechanics adds fringes no orbit can produce — doubling the rate at right angles for one kind of particle and halving it for the other.

quantum · Correspondence

Named alongside it

The objects these essays reach for when they reach for this one.

Screening Atomic structure Binding energy Bohr radius The Boltzmann factor Classical limit Collective behaviour Correspondence principle Cross-section Debye length Electron shell Identical particles

All concepts