The collection

Every essay — page 19

One idea per essay, ordered so that the earlier ones set up the later ones — but nothing here depends on being read in sequence.

Mechanics

Motion, force, and the quantities that refuse to change.

Waves

Oscillation, and everything that turns out to be an oscillation.

Two states at zero that only one side of the chain has. Every energy level of a chain of 20 cells, 40 sites, whose couplings alternate between v inside a cell and w = 1 between cells, against the ratio v/w from 0 to 2. The bulk levels fill two bands, bounded by the dashed lines ±|v − w| and ±(v + w), with a gap between them that closes at v = w. For v < w two levels sit at zero energy, in the middle of the gap, drawn in the warning colour: at v/w = 0.5 they are within a millionth of the coupling of zero. For v > w the gap is empty — at v/w = 1.5 the nearest level to zero is 0.527. Nothing about the chain's middle distinguishes the two sides of v = w; the difference is at its ends.

The end that knows how the middle was cut

A chain whose links alternate, strong and weak, has the same bands whichever kind of link is counted as inside a cell. The infinite chain cannot tell the two choices apart. A finite chain can: cut it so that a weak link is outermost and each end holds a state at exactly zero energy, in the middle of the gap; cut it the other way and it holds none. What decides is not anything at the ends but a whole number counted from the bulk — how many times a loop winds round a point.

5 figures · part 4 on Periodic media
A gap that every angle from air falls into. The stop bands of a stack of quarter-wave layers of index 4.6 and 1.6 — tellurium and polystyrene, the pair of the first such mirror — against frequency, in units of the design frequency, and the parallel index β = n₀ sin θ₀ the light brings along the layers; TE polarisation on the right, TM on the left. Shaded regions are gaps. Light from air can only have β between −1 and 1, the vertical lines; within those lines the gaps for both polarisations overlap between f = 0.848 and 1.321, the band marked across the figure, so every angle of incidence and both polarisations are reflected: a relative width of 43.6%. The TM gap narrows as β grows and closes at the internal Brewster index, 1.51, which light from air cannot reach.

The mirror that works from every direction

A stack of alternating transparent layers reflects nearly all the light of one colour arriving straight on, and less as the light tilts, because tilting moves the forbidden band. A structure that repeats in only one direction ought therefore to be a mirror for only a range of directions. It is not, if the layers differ enough: light arriving from air cannot bring enough sideways momentum to escape the forbidden band at any angle, for either polarisation, and a flat stack of plastic and tellurium reflects every angle over a band of frequencies almost half as wide as its centre.

5 figures · part 5 on Periodic media
One width that falls to nothing. The decay rates of the two modes of a pair of resonances that leak into one shared channel at rates 0.1 and 0.05 and are coupled to each other with strength 0.2, against the detuning of the first from the second. The two rates always add to 0.15, the trace of the leak matrix, to 10⁻¹². Where the resonances are far apart each mode keeps roughly its own resonance's leak. Near them the leaks interfere, and at a detuning of 0.1414 — κ(γ₁ − γ₂)/√(γ₁γ₂) — the slower mode's decay rate is zero to within 10⁻¹², and the faster carries all 0.15. That mode sits at a frequency where the channel is open and does not leak into it: the two routes by which it could escape cancel.

The resonance that refuses to leak

A resonance that sits at a frequency where waves can escape has a width, because it leaks. Put two such resonances into the same channel and let them talk to each other, and at one precise detuning one of their combinations stops leaking altogether — a mode with no width, surrounded by a continuum it could escape into and does not. It cannot be seen from outside, it traps whatever energy lands in it, and if a symmetry is what forbids the leak, it survives any change that keeps the symmetry.

5 figures · part 6 on Resonance
How close a network gets to a load that stores charge. The fraction of a wave's amplitude reflected from a resistance shunted by a capacitance, with RCωc = 2, against frequency in units of the band edge ωc, for the load alone and for networks of inductors and capacitors whose values, with an ideal transformer at the source, were optimised numerically to keep the reflection low across the band. The bare load holds it to 0.707 across the band; the 1-element network holds it to 0.392 across the band; the 2-element network holds it to 0.320 across the band; the 3-element network holds it to 0.289 across the band. The dashed line is Bode and Fano's floor, exp(−π/RCωc) = 0.208, which no network of any size can go beneath over the whole band; each added element brings the design closer to it, and each buys its flatter band with a reflection that climbs to total just beyond the band edge.

The mismatch no network can remove

A quarter-wave layer or a taper can match a resistance to a resistance as well as anyone likes. Put a capacitance across the load and that stops being true for every network that could ever be built from lossless parts: Bode and Fano proved that the total amount of match available is fixed by the load's resistance and capacitance, so a network can only move it about — and a flat match across a band can never be better than e to the minus π over the load's time constant times the band.

4 figures · part 4 on Impedance
One slit, four distances, one multiplication. The intensity across the beam behind a slit 5 wavelengths wide, at distances of 0.5, 5, 25, 100 wavelengths, each computed by multiplying the slit's plane-wave spectrum by the phase each wave accumulates and transforming back — no approximation about angles. Close to the slit the pattern is the slit's own shape with ripples at its edges; further out the ripples move inwards and the beam develops a bright centre; far away it spreads into the diffraction pattern. The travelling part of the field keeps its power to 10⁻¹⁰, running it back 100 wavelengths recovers it to 5 × 10⁻¹⁴, and at 100 wavelengths the result matches a direct Fresnel integral to 2.75 per cent rms. Near field and far field are not two theories; they are one multiplication at different distances.

The fan of plane waves inside every beam

Huygens added up wavelets from every point of a front. The same content can be written as a sum over plane waves travelling in every direction, and then propagation stops being an integral and becomes a multiplication: each plane wave picks up a phase in proportion to the distance. One square root in that phase holds all of diffraction, near field and far field alike — and when the square root turns imaginary, it holds the reason no instrument a wavelength away can see detail finer than half a wavelength.

4 figures · part 5 on Huygens

Optics

Light, and the small number of rules it obeys.

Electromagnetism

Charge, field, and the lines drawn between them.

Thermodynamics

Heat, disorder, and the one law with a direction in it.

Two bodies an engine draws together. Two equal bodies of 4.186 kJ/K — a kilogram of water each — one at 90.0 °C and one at 10.0 °C, against the heat drawn from the hot one. The solid curves are the best possible engine running between them, a reversible one, which leaves the product of the two temperatures unchanged and brings both to the geometric mean, 320.7 K (47.5 °C). It draws 177.8 kJ from the hot body and delivers 20.8 kJ of work, C(√T₁ − √T₂)², checked against the heat balance. The dashed lines are the same bodies simply touching: they meet at the arithmetic mean, 323.1 K, having exchanged 167.4 kJ and delivered nothing. The 2.5 K between the two endpoints is the work, left behind as heat.

The work left in two buckets of water

Carnot's ceiling assumes reservoirs so large that taking heat from one and giving it to the other changes neither temperature. Two buckets of water are not reservoirs. Run the best possible engine between a hot one and a cold one and both temperatures move, the efficiency available shrinks as they do, and the engine stops when they meet — at the geometric mean of the starting temperatures, not the ordinary one. The work it delivered is exactly the difference between those two meeting points, and it is far less than the starting temperatures promise.

5 figures · part 6 on Heat engines
Two entropies that agree until half filling. The entropy per unit of 100 two-level units against the fraction excited, by Boltzmann's definition, the logarithm of the number of arrangements at that energy, and by Gibbs's, the logarithm of the number at or below it. Below half filling they nearly coincide: at a quarter excited they are 0.538 and 0.542 per unit, and both approach the dashed large-system curve. Boltzmann's entropy then turns over and falls back to zero when every unit is excited; at three-quarters it is 0.538. Gibbs's cannot fall, because a running total cannot, and it levels off at ln 2 = 0.693, reaching 0.693 at three-quarters. The slope of each is one over its temperature.

The count that decides which entropy is right

There are two ways to count the states of an isolated system: the states at its energy, which is Boltzmann's entropy, and the states at or below it, which is Gibbs's. For large systems in ordinary conditions they agree to the last measurable digit. For a system whose energy has a ceiling, past the halfway point, one gives negative temperatures and the other forbids them. Definitions cannot settle which is right, but a temperature is for something — saying which way heat will flow — and putting two such systems in contact lets the count of states answer.

5 figures · part 6 on Third law
Nitrogen that runs the wrong way. The nitrogen mole fraction in each of two bulbs joined by a capillary, as in Duncan and Toor's experiment: one bulb starts with 0.50086 nitrogen and the rest carbon dioxide, the other with 0.49879 nitrogen and the rest hydrogen, at 35 °C. Solid curves: the capillary solved at each instant from the Maxwell–Stefan equations with the three pairs' diffusivities, 83.8, 68.0 and 16.8 mm²/s. Dashed: Fick's law for nitrogen alone, which can only let the two start values relax together. At the start the nitrogen gradient is 0.00207, yet nitrogen flows at 309 times the rate that gradient would drive. From 0.1 to 6.5 hours it flows from the bulb with less nitrogen into the bulb with more, opening a difference of 0.1468 at 6.5 hours; at 6.6 hours its flux passes through zero with a difference of 0.1468 still in place. Each gas is conserved to a part in 10⁹. The carbon dioxide moving out of the first bulb drags nitrogen with it, because the nitrogen–carbon dioxide pair has by far the smallest diffusivity and so the strongest friction.

The gas that flows towards more of itself

Fick's law says a substance diffuses from where there is more of it to where there is less. In a mixture of three gases, nitrogen can do the opposite for hours — flowing into the bulb that already holds more nitrogen, and then stopping while a difference remains — and in a welded bar of steel, carbon crosses into the side that is already richer. Nothing is wrong with the second law. Diffusion flattens chemical potential, and with more than two components, or a second element changing it, that is not the same as flattening concentration.

4 figures · part 7 on Diffusion

Relativity

Space and time, drawn on the same axes.

Quantum

Where the continuous picture runs out, and what replaces it.

Fluids

Matter that will not hold a shape, and the forces that act in it anyway.

Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

The stretch a chain cannot outrun

A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

5 figures · part 5 on Rheology
Most of a chain's counterions never leave it. The fraction of a charged rod's counterions lying within a distance r of it, against r in rod radii on a logarithmic axis, for a charge parameter ξ = 4.2 — the Bjerrum length of water, 0.7135 nm, over a charge spacing of 0.17 nm, which is DNA's. Each curve is the Poisson–Boltzmann solution for the rod at the centre of a cell of radius 10², 10⁴, 10⁶ rod radii, with its counterions checked to neutralise it exactly. Diluting the solution widens the cell by four decades at a time, and a counterion free to go anywhere in the cell ought to spread with it; instead each curve keeps a plateau near the rod whose height does not change. At the inflection of every curve the enclosed fraction is 0.762, which is Manning's 1 − 1/ξ, and the plateau sits there: 76 per cent of the counterions stay bound to the chain however dilute the solution, and only 24 per cent spread through it.

The counterions that never leave the chain

Dilute a solution of DNA a million times and its counterions ought to scatter through the whole volume. Three quarters of them do not. A line of charges closer together than the Bjerrum length — 0.71 nm in water — holds on to its counterions however much room they are given, until the chain's charge is cut back to one per Bjerrum length, and every osmotic pressure, swelling gel and packed virus built from such chains is set by that length rather than by the chemistry.

5 figures · part 5 on Osmosis
The latitude past which the tide cannot shed its energy by halves. Frequency in cycles per day against latitude. The curve is the inertial frequency, 2Ω sin(latitude), below which no internal wave can oscillate; the shaded region above it is where internal waves exist. The horizontal lines are the semidiurnal and diurnal tides and the frequencies half of each, where a parametric instability would put the waves the tide decays into. Each line ends where it meets the curve, which is its critical latitude: M2, semidiurnal at 1.932 per day, 74.5°; M2 ÷ 2 at 0.966 per day, 28.8°; K1, diurnal at 1.003 per day, 30.0°; K1 ÷ 2 at 0.501 per day, 14.5°. Equatorward of 28.8° the semidiurnal tide can feed waves at half its frequency; poleward of it those waves cannot exist and that route is closed. The diurnal tide's subharmonic is confined within 14.5° of the equator, and the diurnal tide itself cannot propagate as a free internal wave poleward of 30°.

The latitude past which a tide cannot split

The ocean's internal tide carries about a terawatt, and somewhere it has to be broken into waves small enough to mix the water. One of the ways it breaks is by pumping waves at half its own frequency, the way a child on a swing pumps at twice the swing's. Those half-frequency waves cannot exist where the planet's rotation forbids oscillations that slow — poleward of 28.8° for the semidiurnal tide — so the route has an edge on the map, fixed by the Moon's period and the Earth's spin.

5 figures · part 5 on Stratification

Astrophysics

Gravity read as geometry, and the laws carried where no laboratory can follow.

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