Concept

Thin film interference — where it appears

Colour and reflection produced when light reflected from the top and bottom of a layer about a wavelength thick interferes with itself. It makes soap bubbles iridescent, lets anti-reflection coatings work, and turns stacks of layers into mirrors.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

The colours a draining film runs through, and the end of them. The fraction of light a free soap film reflects, against its thickness, at three wavelengths — 450, 550, 620 nm — computed from the sum over multiple reflections rather than from the two-beam approximation. The three curves peak at different thicknesses, which is why a draining film runs through a sequence of colours as it thins. Below about 11 nm every curve is under a tenth of a per cent and the film looks black. At zero thickness the reflectance is exactly zero, checked before the figure is drawn: the two surfaces reflect equally and half a cycle out of step, so a film much thinner than a wavelength cancels itself. That is the whole of why a black film is black. Nothing is absorbing; the film is there and has simply stopped being able to interfere constructively at any visible wavelength — which means the blackness is a measurement, and a film that has gone black is known to be thinner than about a tenth of a wavelength without anything being measured directly.

The film that goes black before it bursts

A soap film drains, runs through every interference colour, and then stops reflecting anything at all. The black patch is not a hole and not a film about to break: it is the thinnest and most stable state the arrangement has, held apart by a pressure between its two surfaces that only exists at distances of nanometres.

fluids · Surface tension
A gap that every angle from air falls into. The stop bands of a stack of quarter-wave layers of index 4.6 and 1.6 — tellurium and polystyrene, the pair of the first such mirror — against frequency, in units of the design frequency, and the parallel index β = n₀ sin θ₀ the light brings along the layers; TE polarisation on the right, TM on the left. Shaded regions are gaps. Light from air can only have β between −1 and 1, the vertical lines; within those lines the gaps for both polarisations overlap between f = 0.848 and 1.321, the band marked across the figure, so every angle of incidence and both polarisations are reflected: a relative width of 43.6%. The TM gap narrows as β grows and closes at the internal Brewster index, 1.51, which light from air cannot reach.

The mirror that works from every direction

A stack of alternating transparent layers reflects nearly all the light of one colour arriving straight on, and less as the light tilts, because tilting moves the forbidden band. A structure that repeats in only one direction ought therefore to be a mirror for only a range of directions. It is not, if the layers differ enough: light arriving from air cannot bring enough sideways momentum to escape the forbidden band at any angle, for either polarisation, and a flat stack of plastic and tellurium reflects every angle over a band of frequencies almost half as wide as its centre.

waves · Periodic media
Light added to its own reflection. Green light of 550 nm in an emulsion of refractive index 1.5, falling on a metal mirror at the left and adding to its reflection, which comes back inverted. Thin lines: the total electric field across the first 750 nm at three moments; heavy line: its envelope, 2|sin kz|; dashed: the envelope of the magnetic field, 2|cos kz|. The sum does not travel. Its electric field is zero at the mirror at every instant and again every 183 nm, half a wavelength in the emulsion, with maxima between; the magnetic field is largest exactly where the electric field vanishes. A light-sensitive layer anywhere in that space is exposed in sheets parallel to the mirror, and which field it responds to decides whether the first sheet lies at the mirror or a quarter-wavelength above it.

The photograph that keeps the spectrum

Light falling on a mirror adds to its own reflection, and the sum does not travel: it stands, with sheets of darkness every half-wavelength. Otto Wiener photographed those sheets in 1890 and found the film clear where it touched the mirror, which settled which of light's two fields acts on matter. A year later Gabriel Lippmann recorded the sheets through the depth of an emulsion and developed them into stacked layers that, lit with white light, send back exactly the colours that wrote them. His photographs store the spectrum itself, so they can tell apart two yellows that every colour film and every eye records as one.

waves · Superposition

Named alongside it

The objects these essays reach for when they reach for this one.

InterferenceBand gapBragg mirrorBrewster's angleCapillary pressureDisjoining pressureDrainageEquilibriumLight coneNodeOmnidirectional reflectionPhotonic crystal

All concepts