Illustrated Physics
physics, drawn
Concept

Thermal transpiration — where it appears

The pressure difference two vessels at different temperatures settle at when they are joined by a hole smaller than the mean free path. Equal fluxes rather than equal pressures is the equilibrium condition, so P/√T is what matches — and every low-pressure gauge at a different temperature from its vessel reads wrong by that factor.

Named by 3 essays across 2 fields — each of them below, with the objects they name alongside it.

Which grains the light wins. The radiation force on a spherical grain divided by the gravitational force on it, against the grain's radius, on logarithmic axes. Both forces fall as the inverse square of the distance, so the ratio does not depend on how far away the grain is — only on how big it is. Light acts on the cross-section and gravity on the volume, so the ratio goes as 1/a, and the two are equal at 287 nm for material of density 2000 kg/m³. Anything smaller than that is expelled; anything larger stays.

Light has a pressure

Sunlight pushes on a square metre with about the weight of a grain of sand, which sounds like a curiosity until the object being pushed is small enough. The demonstration in every school cupboard turns the wrong way, and the reason it does is more interesting than the effect it is supposed to show.

astrophysics · Radiation pressure The gas that leaves is not the gas inside. The distribution of molecular speeds inside a container at 300 K and in the beam that escapes through a small hole in it, each normalised to its own peak. They are not the same distribution. A molecule's chance of reaching the hole in a given time is proportional to how fast it is going, so the beam carries one more factor of speed than the gas does — v³ rather than v² times the Boltzmann factor — and the beam is therefore faster and hotter than what it came from. The mean speed inside is 476 m/s and in the beam 561 m/s, a ratio of 1.1781 against the exact 3π/8; and the mean kinetic energy is 1.500 kT inside against 2.000 kT in the beam, which are exactly 3/2 and 2. That difference is not a subtlety. A molecular beam made by effusion has a temperature, in the sense of a mean energy, a third higher than its source; a gas slowly leaking from a container leaves the remainder cooler than it would be if a fair sample had gone; and every calculation of a rate through an aperture that uses the bulk distribution is wrong by this factor.

The gas that leaves is not the gas inside

Put a small hole in a container of gas and what comes out is faster and hotter than what stays behind — its mean kinetic energy is 2kT against the 3/2 kT of the gas it came from. Nothing has heated it. A fast molecule simply reaches the hole more often than a slow one, so the sample that escapes is biased by exactly one factor of speed, and every consequence of effusion is that factor.

thermodynamics · Kinetic theory Effusion rate against molecular mass. The rate at which a gas escapes through a small hole, against its molar mass, normalised to hydrogen. The rate is a quarter of the number density times the mean speed times the area, and the mean speed goes as the inverse square root of the mass — so the rate does too, which is Graham's law of 1848. Hydrogen escapes four times faster than oxygen and 13.3 times faster than uranium hexafluoride. The practical consequence is isotope separation, and its difficulty is on this chart. The two uranium hexafluorides differ by 3 out of 352 in mass, so a single stage enriches by a factor of only 1.00429 — four parts in a thousand. Reaching 90 per cent from natural uranium's 0.72 per cent therefore takes about 1665 ideal stages, and a real cascade needs more because each stage is imperfect. That number is why gaseous-diffusion plants were among the largest industrial structures ever built, and why centrifuges — which separate by mass directly rather than by the square root of it — replaced them.

The gradient that drives the other thing

A concentration gradient drives a flow of matter and a temperature gradient drives a flow of heat. Each also drives the other, by coefficients that are equal — a relation nobody could have guessed and which follows from the fact that the underlying motion runs the same forwards and backwards in time.

thermodynamics · Diffusion

Named alongside it

The objects these essays reach for when they reach for this one.

Mean free pathBlackbodyCross-sectionDetailed balanceDiffusionEffusionEntropyEquilibriumFluxGrahams lawIrreversibilityIsotope separation

All concepts