Concept

Superconductivity — where it appears

The state in which a material has exactly zero resistance and expels magnetic field from its interior, below a critical temperature. It is a thermodynamic phase rather than a limit of good conduction, its carriers are pairs of electrons, and the flux through a superconducting ring can only be a multiple of h/2e.

Named by 10 essays across 2 fields — each of them below, with the objects they name alongside it.

The screening that survives to zero frequency. How far a magnetic field gets into copper against how fast it is changing, drawn beside the London depth of a superconductor with a carrier density of 6.0e+28 per cubic metre. The metal's curve falls as one over the square root of the frequency — measured on the drawn curve as -0.5000 against −½ — and it is a straight line on these axes with no bottom: at a hundred hertz the field reaches nine millimetres in, and at zero frequency it reaches all the way through, because a normal metal screens by dissipating and a steady field dissipates nothing. The superconductor's line is flat at 21.7 nanometres. The frequency does not appear in the expression for it, so there is nothing for it to depend on, and the screening is as complete at zero frequency as at any other. The two lines cross at 9.0e+12 hertz, in the far infrared, and above that the ordinary metal is actually the better screen — which is a useful corrective, because a superconductor's advantage is not that it screens harder but that it does not need the field to be changing. What the picture cannot show is where the flat line stops: above the energy gap the pairs break, the superconductor becomes an ordinary metal, and the flat line turns into a sloping one.

The field that is pushed out

A perfect conductor keeps whatever field was inside it when its resistance vanished. A superconductor expels the field either way, and the difference between remembering and expelling is the experiment that showed superconductivity is a state of matter rather than a very good conductor.

electromagnetism · Superconductivity
The size of the quantum says what is carrying the current. What the flux quantum would be for each candidate carrier charge, in units of 10⁻¹⁵ webers, against the measured value drawn as a line. A single electron would give 4.1357, a pair 2.0678, a triple 1.3786. The measurement is 2.0678, which picks the pair and excludes the others by a factor of two — not by a few per cent, so no question of experimental accuracy arises. The whole of the argument is that the condensate's wavefunction must come back to itself round the ring, which makes the enclosed flux a multiple of h over the carrier's charge; measuring the multiple therefore measures the charge, without any charge ever being measured. That is how the pairing was established in 1961, four years after it was proposed and by an experiment that looks nothing like a measurement of a charge.

The two in the flux quantum

A superconducting ring cannot hold whatever flux is applied to it. It holds a whole number of quanta and drives a current to make up the difference, and the size of that quantum is Planck's constant divided by twice the electron's charge. The factor of two was measured in 1961, four years after somebody predicted that the carriers are pairs — by an experiment in which no charge is measured at all.

electromagnetism · Superconductivity
The ring picks a whole number and pays for the difference. The kinetic energy of the screening current in a superconducting ring, against the flux applied from outside, in units of the flux quantum. Each parabola belongs to one winding number — the number of times the condensate's phase turns round the ring, which has to be an integer because the wavefunction has to come back to itself. The ring cannot hold an arbitrary flux, so it holds the nearest whole number of quanta and drives a current to make up the difference; the energy of that current goes as the square of the mismatch, which is what each parabola is. The lowest curve at each applied flux is the state the ring is in, and the winding number changes at exactly the half-integers — 0.50 and 1.50 and 2.50 here. So the measurable properties of the ring are periodic in the applied flux with a period of one quantum, which is 2.0678 × 10⁻¹⁵ webers and is about the flux the Earth's field puts through a square micrometre.

Two lengths, and which one is longer

A superconductor has a depth to which a field leaks in and a distance over which superconductivity itself can be built up. Which of the two is larger decides the sign of the energy of a boundary — and therefore whether the material keeps every field out or fills itself with a lattice of holes.

electromagnetism · Superconductivity
A current with no voltage, and then a voltage that is a frequency. Current against mean voltage for a Josephson junction shunted by a resistance, in units of its critical current and of the critical current times the resistance. Up to the critical current the junction carries a supercurrent at exactly zero voltage, set by the difference of the two superconductors' phases. Above it a mean voltage appears, growing as R√(I² − Ic²) and approaching the ohmic line at large current; the curve is integrated from the junction equation and checked against that result at three currents. The voltage is not steady. It is a train of pulses, each the phase slipping by one turn, at a frequency of 483.6 GHz per millivolt: for a junction with Ic = 1 mA and R = 1 Ω, one unit of the voltage axis is 1 mV and 484 GHz.

The voltage that is a frequency

Two superconductors separated by a barrier a nanometre thick carry a current with no voltage at all, set by the difference of their quantum phases. Push harder and a voltage appears — and a voltage makes that phase difference run, so the current oscillates at 483.6 gigahertz for every millivolt. Shine microwaves on the junction and the voltage locks to exact multiples of the frequency divided by a ratio of fundamental constants, with nothing about the junction in it. That is why a volt is now counted in cycles.

electromagnetism · Superconductivity
A temperature the circuit refuses to go below. The escape temperature — the temperature that would give the measured escape rate if escape were purely thermal — against the actual temperature of the junction, for a 10 µA, 5 pF junction at biases of 0.985 and 0.99 of its critical current. Hot, the two are equal: the phase is kicked over the barrier by thermal noise. Cooled below the crossover, 39 mK at 0.985 and 36 mK at 0.99, the escape temperature stops falling and levels off at 42 mK and 44 mK: the rate no longer depends on the temperature at all. This levelling-off, measured by Michel Devoret, John Martinis and John Clarke in 1985 with the junction's electrical environment carefully characterised, was the evidence that a macroscopic electrical variable tunnels.

The circuit that goes through a wall

Tunnelling is usually told about electrons and alpha particles — single, small, quantum things passing through barriers they cannot climb. In 1985 it was seen in an electrical circuit: the phase difference across a Josephson junction, a coordinate shared by all the electrons in two pieces of superconducting metal, trapped in a well and escaping from it through the barrier rather than over it. The evidence was a temperature below which the circuit's escape rate stopped caring how cold it was. The same circuit showed discrete energy levels, and its descendants are the qubits of superconducting quantum computers.

quantum · Tunnelling
Rotation is a magnetic field, and a superconductor cancels it. Magnetic fields along the spin axis inside a spinning metal, in units of 2mω/e, as seen by its electrons in the frame turning with it. In that frame the Coriolis force on an electron is exactly the force a magnetic field of 2mω/e would exert, pointing against the spin for a negative charge (Larmor's theorem). A normal metal spun in no field has no real field inside, and its electrons feel the rotation's equivalent field in full. A superconductor will not let its carriers feel any field in their interior — that is the Meissner effect — so it generates a real field of exactly the same size pointing the other way, and the sum vanishes. The real field is the London moment.

The field a spinning superconductor makes of itself

Spin a lump of superconductor with no magnet anywhere near it, and a magnetic field appears inside it, pointing along the axis of spin: about eleven trillionths of a tesla for every radian per second, the same in lead, niobium or a copper-oxide ceramic. The field is not left over from anything. In a turning frame the Coriolis force on a moving charge is indistinguishable from a magnetic force, a superconductor will not let its carriers feel any field inside it, and so it makes a real field to cancel the one rotation imitates. The size depends on nothing but the carriers' mass and charge, which makes the field a balance for weighing them — and the one time it was read to a part in a hundred thousand, it gave an answer theory has not matched.

electromagnetism · Superconductivity
The Casimir pressure between warm plates, from vacuum to heat. The attractive pressure between two parallel, perfectly reflecting plates at 300 K against their separation, on logarithmic axes, from the Lifshitz sum over Matsubara frequencies. Dashed: the zero-temperature law π²ħc/240a⁴. Dotted: the classical law ζ(3)kT/4πa³, which contains no Planck constant. At 1 μm the full pressure is 0.0013 Pa, within 0.2 per cent of the vacuum value; at 10 μm it is 3.96·10⁻⁷ Pa, 3.05 times the vacuum value and within 0.002 per cent of the classical law. The two laws cross at 3.28 μm; the thermal length ħc/kT is 7.63 μm. The second solid curve removes one term — the static magnetic fluctuation, which a metal of finite conductivity does not reflect — and sits 15 per cent lower at 1 μm and a factor of two lower far out. The plates are otherwise ideal mirrors: a model, chosen to isolate that one term.

The force that forgets Planck's constant

Two mirrors in a vacuum attract, with a pressure that contains Planck's constant and nothing else about the world but the speed of light. Warm the mirrors and pull them apart, and past a few micrometres at room temperature the Planck constant drops out of the answer. The force is still there and is now larger than the vacuum alone would give, but it has become classical: a count of thermal fluctuations of the static field, with kT of energy each. Half of that classical force comes from one fluctuation — a static magnetic field — and whether a real metal mirror reflects it is a question that has divided the people who measure the force for twenty years.

electromagnetism · Retardation
How a field enters a superconductor that pins it. The magnetic field inside a slab of type-II superconductor, against position across its thickness, as an applied field is raised from zero, in units of the full-penetration field H = Jc a. Each line is the profile at an applied field of 0.5 H, 1.0 H, 1.5 H, 2.0 H. The field enters from both faces as a wedge whose slope is the most current the pinned vortices can carry, Jc; at 0.5 H it reaches halfway to the middle, at H* it just reaches the middle, and beyond that the whole slab carries Jc and the profile rides up with the applied field. A type-I superconductor would show no field inside at all, and a normal metal the applied field everywhere.

The field a superconductor keeps after all

A superconductor is famous for throwing magnetic field out, and the experiment that showed it is the one that made superconductivity a state of matter. Most superconductors that are actually used do something closer to the opposite: they let the field in as threads, grip the threads where they are, and keep them when the field is taken away. The result is a slope of field inside the material that is as steep as the grip allows and no steeper, which is all that is needed to explain why such a superconductor has a hysteresis loop, heats up in an alternating field, can hang a magnet underneath itself, and can be made into a magnet stronger than any of iron.

electromagnetism · Superconductivity
A current limited by the wire's circumference. The largest supercurrent a wire can carry before the field of its own current destroys superconductivity at its surface, Ic = 2πaHc, against the wire's diameter, for lead, mercury and tin at 1.5 K, on logarithmic axes; dashed, a niobium–titanium wire carrying 3,000 A/mm² in a field of 5 tesla, which grows with the cross-section rather than the circumference. A lead wire 1 mm across carries 192 A — 244 A/mm² — and one 1 cm across only ten times as much, at a tenth of the density. Below 81 micrometres lead carries more than niobium–titanium; above it niobium–titanium wins by a factor that grows with the wire, and it does so in a field of 5 tesla, where lead cannot superconduct at all.

The current a superconductor stops with its own field

A superconducting wire has no resistance, so it seems it should carry any current at all. It carries a definite amount and no more, and the amount is set not by the metal's ability to conduct but by the field the current itself makes: when that field at the wire's surface reaches the critical field, superconductivity fails there. The rule makes the largest current proportional to the wire's radius rather than its area, makes a thick wire worse per square millimetre than a thin one, and explains why the first superconducting magnet, wound in 1913, did not work.

electromagnetism · Superconductivity
Flux leaving a plate in stripes and spreading into a uniform field. A cross-section through a superconducting plate in the intermediate state near its top surface (below the line), with a normal fraction of 0.40: normal laminae (shaded) each carry the critical field straight up, the superconducting laminae between them carry none. Lengths are in units of the period of the pattern. Above the surface the field lines (solid) are computed from the stray field of the stripes: they fan out from each normal lamina and close up over the superconducting ones, and within about a third of a period the field is uniform at 0.40 of the critical field — the applied field, which is all a distant observer measures. The fanning field stores energy, and it stores more the wider the stripes are, because a wider pattern's non-uniformity reaches further out. That is half of what sets the period.

The stripes a superconductor makes of a field

A superconductor expels a magnetic field, but only if the field it pushes aside stays below the critical field everywhere at its surface — and for anything but a long rod held along the field, the field it pushes aside piles up at its edges. A flat plate laid across a field cannot expel any of it. It splits instead into interleaved bands of normal metal carrying exactly the critical field and superconducting metal carrying none, in the proportion flux demands, and the bands have a definite width. Walls between the two cost energy and favour few, broad bands; the field fanning out of the surface favours many narrow ones. The compromise is the geometric mean of the plate's thickness and a microscopic length.

electromagnetism · Superconductivity

Named alongside it

The objects these essays reach for when they reach for this one.

Meissner effectCritical fieldFlux quantumCondensateCooper-pairFlux freezingIntermediate stateMacroscopic quantum stateMagnetic fluxOrder parameterPenetration depthPhase coherence

All concepts