Concept

Order parameter — where it appears

A quantity that is non-zero in an ordered phase and zero in the disordered one, and vanishes continuously at a critical point. For a fluid it is the density difference between liquid and vapour, for a magnet the magnetisation, and the exponent with which it vanishes is the same for both.

Named by 5 essays across 3 fields — each of them below, with the objects they name alongside it.

Two transitions, one shape and one not. The condensate fraction of an ideal Bose gas, 1 − (T/Tc)^3/2, drawn against the superfluid fraction of liquid helium-4, which goes as roughly 1 − (T/Tλ)^5.6. Both reach one at absolute zero and zero at their transition, and in between they disagree everywhere. The ideal calculation says why a transition has to exist; it does not describe the one that does, because its atoms do not interact and helium's do.

The liquid that will not slow down

Cool helium below 2.17 kelvin and it starts flowing through gaps no ordinary liquid could enter, climbs out of its own container, and circulates for as long as anyone has been willing to watch. The viscosity is not small. As far as any measurement can tell, it is zero.

quantum · Superfluidity
Two straight lines that are not the same line. Half the difference between the liquid and vapour densities, in units of the critical density, against the distance from the critical temperature — both logarithmic, over 5 decades. The van der Waals curve is solved for the coexisting pair at each temperature and its slope in the last decade is 0.500, which is the mean-field ½. Real fluids give 0.326. The two differ by 11 per cent at t = 0.1 and by a factor of 7.9 at the bottom of the axis, which is why an equation with the wrong exponent in it looked right for eighty years.

The point at which the two become one

Heat a sealed tube of carbon dioxide and the meniscus inside it does not boil away — it fades, the two densities converging until there is nothing to separate. Twenty millikelvin before that happens the fluid turns milky, and the exponent describing the last approach is a number van der Waals got wrong and could not have got right.

thermodynamics · Phase change
A stiffness that does not go to zero — it falls off a cliff. The renormalised stiffness of a two-dimensional superfluid against temperature, obtained by integrating the flow of the bare stiffness and the vortex fugacity, with the bare stiffness drawn for comparison. Below the transition the vortices are bound in pairs, screen one another and leave a finite stiffness; above it they unbind and there is none. What is remarkable is the value at which it disappears: 0.6430, against 2/π = 0.6366. That number does not depend on the material, on the bare fugacity, on the core energy, or on anything else — every two-dimensional superfluid loses its stiffness at exactly two over π times its own transition temperature, and measurements on helium films of widely different thicknesses fall on that line. A transition at which a quantity jumps to zero from a value nobody can adjust is unlike anything the usual classification of transitions describes.

The transition with nothing to order

Every transition in this collection so far has an order parameter — a quantity that is zero on one side and not on the other. In two dimensions a continuous symmetry cannot break at any temperature above zero, so there is nothing for such a quantity to be, and by the usual reckoning there can be no transition. There is one anyway, and what changes at it is whether vortices are bound in pairs.

thermodynamics · Phase change
The ring picks a whole number and pays for the difference. The kinetic energy of the screening current in a superconducting ring, against the flux applied from outside, in units of the flux quantum. Each parabola belongs to one winding number — the number of times the condensate's phase turns round the ring, which has to be an integer because the wavefunction has to come back to itself. The ring cannot hold an arbitrary flux, so it holds the nearest whole number of quanta and drives a current to make up the difference; the energy of that current goes as the square of the mismatch, which is what each parabola is. The lowest curve at each applied flux is the state the ring is in, and the winding number changes at exactly the half-integers — 0.50 and 1.50 and 2.50 here. So the measurable properties of the ring are periodic in the applied flux with a period of one quantum, which is 2.0678 × 10⁻¹⁵ webers and is about the flux the Earth's field puts through a square micrometre.

Two lengths, and which one is longer

A superconductor has a depth to which a field leaks in and a distance over which superconductivity itself can be built up. Which of the two is larger decides the sign of the energy of a boundary — and therefore whether the material keeps every field out or fills itself with a lattice of holes.

electromagnetism · Superconductivity
A current with no voltage, and then a voltage that is a frequency. Current against mean voltage for a Josephson junction shunted by a resistance, in units of its critical current and of the critical current times the resistance. Up to the critical current the junction carries a supercurrent at exactly zero voltage, set by the difference of the two superconductors' phases. Above it a mean voltage appears, growing as R√(I² − Ic²) and approaching the ohmic line at large current; the curve is integrated from the junction equation and checked against that result at three currents. The voltage is not steady. It is a train of pulses, each the phase slipping by one turn, at a frequency of 483.6 GHz per millivolt: for a junction with Ic = 1 mA and R = 1 Ω, one unit of the voltage axis is 1 mV and 484 GHz.

The voltage that is a frequency

Two superconductors separated by a barrier a nanometre thick carry a current with no voltage at all, set by the difference of their quantum phases. Push harder and a voltage appears — and a voltage makes that phase difference run, so the current oscillates at 483.6 gigahertz for every millivolt. Shine microwaves on the junction and the voltage locks to exact multiples of the frequency divided by a ratio of fundamental constants, with nothing about the junction in it. That is why a volt is now counted in cycles.

electromagnetism · Superconductivity

Named alongside it

The objects these essays reach for when they reach for this one.

Phase transitionQuantisationSuperconductivityUniversalityBose einstein condensationCirculationCompressibilityCondensateCorrelation functionCorrelation lengthCritical exponentCritical line

All concepts