Quantum

The fall that leaves the mass in the phase

Every body falls the same way whatever its mass, and a neutron is no exception. But a neutron is also a wave, and the phase that wave accumulates while falling depends on the mass — as its square, at a fixed wavelength. Tilt a neutron interferometer so that one path runs a centimetre higher than the other and the neutrons swing between its two detectors, which in 1975 was the first measurement in which gravity and quantum mechanics both had to be right at once.

Assumes: Everything has a wavelength, and almost nothing shows it · The phase a magnet leaves on a path it never touched

A feather and a hammer fall together on the Moon, and the fall that does not depend on what is falling has been tested to a part in 101510^{15} with objects of every composition. The mass that measures a body’s inertia is the mass that gravity pulls on, and so it cancels from every trajectory in a uniform field.

A neutron obeys that rule, and a neutron is also a wave with a wavelength of its own. The trajectory of a wave is where its phases add up, and the phase of a matter wave is the action along its path divided by Planck’s reduced constant. The action contains the mass. So the mass cancels from where the neutron goes and survives in how the wave’s phase accumulates on the way — and a neutron interferometer, which compares the phase along two paths, can see gravity acting through the mass on a quantum phase.

In 1975 Roberto Colella, Albert Overhauser and Samuel Werner did exactly that, with neutrons from a research reactor passing through an interferometer cut from a single crystal of silicon. They tilted the interferometer so that one path ran higher than the other and watched the neutrons move from one detector to the other. It was the first experiment whose result depended both on Newtonian gravity and on the quantum mechanics of the particle it acted on.

Two paths at two heights

The interferometer is a block of perfect silicon with three thin slabs standing up from a common base. Neutrons diffract at the first slab into two beams, which the second slab turns back towards each other and the third recombines, so the two paths enclose a diamond a few centimetres across. Two detectors count the neutrons leaving the last slab in two directions, and the ratio between them depends on the phase difference between the paths.

Two paths through a neutron interferometer at two heights. A neutron interferometer cut from one silicon crystal, tilted by 30 degrees about its incoming beam so that one path runs higher than the other. Left: the two paths, split at the first slab, turned at the second and recombined at the third, enclosing 10.1 square centimetres; the heights are drawn exaggerated. Taken as a rectangle of the same area, the upper path runs 15.8 mm higher for 3.2 cm. There a neutron of wavelength 1.445 Å, moving at 2738 m/s, is slower by 56.5 micrometres per second, so its wavelength is longer by 20.6 parts per thousand million. Over 3.2 cm that accumulates 28.7 radians less phase than the lower leg — 4.6 whole fringes — computed by integrating the local wavenumber along both legs and checked against 2πm²gλA sin α / h².
Fig. 1 The two paths through a silicon neutron interferometer tilted by 30° about its incoming beam, heights exaggerated, and the numbers that follow: the height difference, how much slower the neutrons are on the higher path, and the phase that difference accumulates.

With the block level both paths are at the same height. Tilted by an angle α\alpha about the incoming beam, one path is lifted above the other, and a neutron on the higher path has climbed against gravity and is slower. At 30° of tilt, for the 10.1 square centimetres the 1975 interferometer enclosed, the effective height difference is 15.8 millimetres, and a neutron of wavelength 1.445 ångströms travelling at 2,738 metres per second is slower on the higher path by 56.5 micrometres per second. Its wavelength is longer by twenty parts in a thousand million.

That is nothing, by any direct measure, and over 3.2 centimetres of path it adds up to 28.7 radians of phase — more than four and a half whole fringes. The number in the figure was computed by integrating the neutron’s local wavenumber along both paths, not from a formula, and agrees with the closed form

Δϕ=2πm2gλAsinαh2\Delta\phi = \frac{2\pi\, m^2 g\, \lambda\, A \sin\alpha}{h^2}

to a part in ten thousand. The formula depends only on the enclosed area and the tilt, not on the shape of the diamond, which is why the paths can be replaced by a rectangle of the same area for the calculation.

Why a neutron

The choice of particle was not a matter of convenience, and the reasons say something about how weak gravity is.

A charged particle is hopeless. The electric force on an electron in a field of one volt per metre — far weaker than the stray fields on any laboratory surface — is about twenty thousand million times its weight, so any phase gravity writes into an electron wave is buried under phases from fields nobody can fully control. The neutron has no charge. It has a magnetic moment, which the experiments had to shield, but it feels neither the electric fields of the apparatus nor the image charges of nearby conductors.

A neutron is also heavy for a quantum particle — eighteen hundred times the electron’s mass — and the phase grows as the mass squared. And thermal neutrons from a reactor have wavelengths of an ångström or two, comparable with the spacing of atoms in a crystal, so they diffract cleanly from the planes of a perfect silicon lattice and pass through centimetres of it with little absorption. That combination made possible the interferometer Helmut Rauch and his colleagues first operated in 1974, adapting a design already used for X-rays: three slabs cut from one crystal, so that their lattice planes are aligned to a fraction of an atomic spacing across the whole device, which is what keeps two paths centimetres apart coherent with each other.

The same instrument was used in the same years to show that a neutron’s wavefunction changes sign when its spin is turned through a single full rotation, by precessing the spin on one path in a magnetic field and watching the fringes. Gravity and spinor rotation were measured with the same slab of silicon within a year of each other.

Tilting sweeps the neutrons between detectors

Tilting the interferometer sweeps the neutrons from one detector to the other. The share of neutrons arriving at each of the interferometer's two detectors, against the tilt of the interferometer about its incoming beam, for 1.445 Å neutrons with a 1 per cent spread of wavelengths and an enclosed area of 10.1 cm². Level, both paths are at the same height and, with no other phase between them in this idealisation, every neutron reaches detector one. Tilted, the gravitational phase grows as the sine of the tilt and the neutrons swing between the detectors, 7.7 times over the 50° drawn; the two detectors' shares always add to one. The fringes fade with tilt — to a visibility of 0.97 at 25° — because neutrons of slightly different wavelengths acquire slightly different phases, and the fading was computed by averaging over the spread.
Fig. 2 The share of neutrons reaching each of the two detectors as the interferometer is tilted from −25° to +25°, for 1.445 Å neutrons with a one per cent spread of wavelengths. The two shares always add to one. The fringes fade slightly with tilt because neutrons of different wavelengths acquire different phases.

Tilting the interferometer from one side to the other sweeps the gravitational phase through 48.5 radians, and the neutrons swing between the two detectors seven and a half times. The two detectors’ shares always add to one, because every neutron leaves by one exit or the other; what gravity changes is which.

The fringes fade as the tilt grows. The neutrons in any real beam have a spread of wavelengths, about one per cent here, and since the phase is proportional to the wavelength, neutrons at the two edges of the spread acquire slightly different phases and their fringes drift apart. At 25° the visibility has fallen to about 0.97 of its value when level. That fading is itself a check on the scaling with wavelength: a phase that did not depend on λ\lambda would not wash out this way.

Where the mass comes back in

The formula contains the mass squared, and the reason is instructive. The phase of a matter wave along a path is its action divided by \hbar, and for a particle in a uniform field the action is (12mv2mgy)dt\int (\tfrac12 m v^2 - mgy)\,\mathrm{d}t — mass times something that depends only on the path. The trajectory is where that phase is stationary, and stationarity of mm times a function is stationarity of the function: the mass factors out, and every body follows the same path. That is the equivalence principle, recovered from the wave.

The difference in phase between two paths is not a stationarity condition. It is the action difference itself, divided by \hbar, and the mass sits in front of it. One factor of mm comes from there. The second comes from converting a path length into a time: at a fixed wavelength the neutron’s speed is h/mλh/m\lambda, so a heavier particle of the same wavelength is slower and spends longer on the higher path.

The mass cancels from the fall and not from the phase. The gravitational phase across the same interferometer, 10.1 cm² held vertical, for particles of different mass, on logarithmic axes. The steeper line holds every particle's wavelength at the neutron's 1.445 Å, and the phase grows as the square of the mass. The shallower line holds every particle's speed at the neutron's 2738 m/s, so the wavelength shrinks as the mass grows, and the phase grows as the mass. Electron: 1.7·10⁻⁵ rad at fixed wavelength, 0.0312 rad at fixed speed; neutron: 57.4 rad at fixed wavelength, 57.4 rad at fixed speed; helium atom: 904 rad at fixed wavelength, 228 rad at fixed speed; rubidium atom: 4.26·10⁵ rad at fixed wavelength, 4948 rad at fixed speed; caesium atom: 9.97·10⁵ rad at fixed wavelength, 7566 rad at fixed speed; C₆₀ molecule: 2.93·10⁷ rad at fixed wavelength, 4.1·10⁴ rad at fixed speed. Over the same flight every one of them falls by the same 0.67 nanometres, whatever its mass — the classical statement of the equivalence principle — while the phase that records the fall depends on the mass divided by Planck's constant.
Fig. 3 The gravitational phase across the same interferometer, held vertical, for particles from the electron to a C60\mathrm{C}_{60} molecule, on logarithmic axes. At the neutron’s wavelength it grows as the square of the mass; at the neutron’s speed, as the mass. Every one of them falls by the same distance over a leg.

At the neutron’s wavelength the phase grows from 57.4 radians for a neutron to 904 for a helium atom and 430,000 for a rubidium atom, and falls to a hundred-thousandth of a radian for an electron. At the neutron’s speed the growth is linear. And every one of those particles, over a single 3.2-centimetre leg, falls by the same 0.67 nanometres. The fall is the classical content; the phase is what quantum mechanics adds, and it is a measurement of m/m/\hbar as much as of gg.

That is sometimes described as a violation of the equivalence principle, and it is not one. The principle in its operational form says that no local experiment can tell a uniform gravitational field from a uniform acceleration, and that remains true of the phase: an interferometer accelerated upward at gg in empty space would show exactly the same fringes, and the equivalence was checked with a neutron interferometer in 1983 by accelerating it rather than tilting it. What the mass dependence shows is that “falls the same way” is a statement about trajectories, and that a wave has properties beyond its trajectory in which the mass is not hidden. It is the gravitational counterpart of the phase a magnet leaves on a path it never touched: a potential that shows up in the phase, where the classical description sees only forces.

What else turns the phase

A laboratory on the Earth is not an inertial frame, and gravity is not the only thing that changes the phase when the interferometer is reoriented.

What the phase is made of: gravity, and the turning of the laboratory. The two largest phases a neutron interferometer of 10.1 cm² acquires when stood vertical, for 1.445 Å neutrons at latitude 42.3°. Gravity contributes 57.4 radians, from the height difference between the paths. The Earth's rotation contributes 1.73 radians, the Sagnac effect for matter: the laboratory turns under the neutrons while they are in flight, by 3.0 per cent of the gravitational phase. It does not depend on the neutrons' wavelength, where the gravitational phase does, and that difference is how the two are told apart in a measurement.
Fig. 4 The two largest contributions to the phase of a 10.1 cm² neutron interferometer stood vertical at latitude 42.3°: gravity, from the height difference between the paths, and the Earth’s rotation, which turns the laboratory under the neutrons while they fly.

While a neutron crosses the interferometer the Earth turns, and the path that runs with the rotation is effectively longer than the one against it. That is the Sagnac effect, familiar from light sent both ways round a turning loop, here for a massive particle. For the interferometer drawn it contributes 1.73 radians, three per cent of the gravitational phase at full tilt. It was measured separately with neutrons in 1979. It can be told apart because it does not depend on the neutrons’ wavelength — a heavier or slower particle spends longer in flight, but the phase from rotation depends on mass and area only — while the gravitational phase is proportional to the wavelength.

The precision experiments that followed found something less tidy. The measured gravitational phase came out about one per cent below the prediction, a discrepancy far larger than the statistical errors. Most of it was traced to the interferometer itself: a silicon block sags under its own weight by amounts that change as it is tilted, and neutron diffraction in a thick perfect crystal carries phase shifts of its own that depend on the geometry. Whether every part of the residual has been accounted for was argued for years, and it is the reason the best measurements of this kind are now made with atoms, where the paths are defined by laser beams rather than by a crystal.

From a test to an instrument

The neutron experiment established the effect. Its size, 57 radians, is set by a few centimetres of path and twenty microseconds of flight, and there is little room to make either larger with neutrons from a reactor.

From a test of gravity to an instrument for measuring it. The gravitational phase accumulated in three matter-wave interferometers, on a logarithmic scale. The 1975 neutron interferometer: 57 radians, with the neutrons in flight for about 0.02 ms. A rubidium atom gravimeter whose laser pulses are 0.1 s apart: 1.58·10⁶ radians. A ten-metre atomic fountain with pulses a second apart: 1.58·10⁸ radians. Each atom phase is k g T², with k the wavenumber of the two-photon kick from 780 nm light, and grows as the square of the time the atoms fall freely. Read to a thousandth of a radian, the fountain's phase is a measurement of g to 6.3·10⁻¹² of itself.
Fig. 5 The gravitational phase in three matter-wave interferometers, on a logarithmic scale: the 1975 neutron interferometer, an atom gravimeter whose laser pulses are 0.1 s apart, and a ten-metre atomic fountain with pulses a second apart.

Atom interferometers remove both limits. A cloud of laser-cooled atoms is dropped or launched upward, and pulses of laser light act as the beam splitters and mirrors, giving each atom a kick of two photon momenta and later taking it back. The gravitational phase is then the kick’s wavenumber times gg times the square of the time between pulses. With rubidium and pulses a tenth of a second apart it is about 1.6 million radians; in a fountain ten metres tall with pulses a second apart, 160 million. Read to a thousandth of a radian, the fountain measures gg to a few parts in 101210^{12}.

The way the phase arises in an atom interferometer makes the equivalence principle almost visible. Each laser pulse imprints the local phase of the light onto the part of the atom it kicks, and that phase is set by where the atom is when the pulse arrives. Three pulses, a time TT apart, read the atom’s height three times: at the first split, at the mirror pulse in the middle, and at the final recombination. The interferometer’s phase is the wavenumber times the first height, minus twice the middle one, plus the last — a second difference of the trajectory, which for a body in free fall is exactly gT2-gT^2. What the atoms record is their own acceleration relative to the laser’s wavefronts, which are fixed to the apparatus. Accelerate the apparatus upward instead of letting gravity pull the atoms down and the second difference is the same, which is why an atom gravimeter cannot, even in principle, tell the two apart. The mass has dropped out here because the laser, not the atom’s own motion, sets the phase; it is still in the recoil velocity that separates the two paths and in every correction beyond the leading term.

Atom gravimeters are now instruments rather than demonstrations, used in geophysical surveys and to measure the gravitational constant — a counterpart to clocks that measure a height, reading the potential’s slope where the clocks read the potential itself. And they have returned to the question the neutron experiment opened. Dropping two isotopes of rubidium together in the same fountain and comparing their phases tests whether atoms of different mass fall the same way, and has done so at the level of a part in 101210^{12}. In 2022 an atom interferometer measured a phase shift from the gravitational potential of a nearby mass in a region where the force from that mass was negligible — the gravitational version of the effect a magnet leaves on a path it never touches.

What the calculation takes as given

Gravity is uniform across the interferometer. Over a few centimetres the change in gg is a part in 10810^{8}, and it matters only for the atomic fountains, where the atoms rise metres and the gradient of gravity — the part of the field free fall cannot remove — contributes a phase of its own that has to be modelled and removed.

The neutron is a point particle with no internal structure that gravity could act on. It has a magnetic moment and a spin, and in the presence of stray magnetic fields both add phases that the experiments had to shield against.

The wavelength spread is Gaussian and one per cent wide. The fading of the fringes depends on the real spectrum of the beam, and a spread with long tails washes the fringes out differently. The shape drawn is illustrative, and the phase at each wavelength is what the measurement actually tests.

Nothing but gravity and rotation acts on the paths. The crystal’s sag and the dynamical phases of diffraction are left out of every figure, although they are the largest systematic effects in the real measurement.

Two paths drawn where the neutron took neither

The diamond in the first figure is drawn with its height difference exaggerated enormously: a millimetre-scale difference on a few centimetres of path, drawn as a third of the width. More importantly, it draws two paths as though the neutron took one or the other. The interference is the evidence that each neutron does neither; the paths are a bookkeeping device for the two amplitudes whose phase difference the detectors read, and the fringes exist only because no measurement determines which was taken.

The mass chart puts particles on one axis that could never share an interferometer. An electron in a silicon crystal is not a free particle, a rubidium atom cannot diffract from a slab of silicon, and a C60\mathrm{C}_{60} molecule at the neutron’s wavelength would be moving far too slowly to cross anything in a reasonable time. The chart is a statement about how the phase scales, not a menu of experiments.

Still open: whether gravity itself can carry quantum superposition

Every experiment described here puts a quantum particle in a classical gravitational field — the Earth’s, or a test mass’s — and every one of them is consistent with gravity being described classically while matter is described quantum mechanically. That the phase depends on m/m/\hbar says that matter is quantum. It says nothing about whether the gravitational field is.

Proposals made since 2017 would test that directly. Two small masses, each put into a superposition of two positions, would interact only through gravity; if gravity can be in superposition, the two masses would become entangled, and if it cannot, they would not. The masses need to be large enough to produce a measurable gravitational interaction in the time their superpositions survive — about ten picograms each, held in superpositions hundreds of micrometres wide for a few seconds — which is many orders of magnitude beyond anything achieved. Whether gravity can entangle matter is therefore an open experimental question, and the neutron interferometer is where the thread that leads to it began.

The habit worth carrying away is to ask where a quantity cancels. The mass cancels from the equation of motion and not from the action, and so it cancels from trajectories and not from phases. Any wave-like description of matter will show the mass wherever it compares two paths, and the equivalence principle survives as a statement about what trajectories look like, which is all it was ever tested as before 1975.

Part 4 of 4

This essay is one argument about Matter waves. The others:

The objects named here

The third axis, after the field and the reading path: the things themselves, and every essay that touches each one.

ActionAtom interferometryEquivalence principleGravimetryMatter waveNeutron interferometryPhaseSagnac effect