Concept

Thin film — where it appears

A layer whose thickness is comparable to a wavelength, so that the reflections from its two faces interfere rather than adding as intensities. One of the two reflections suffers a half-wave shift, which is why a film thinning to nothing goes black rather than bright before it breaks.

Named by 5 essays across 4 fields — each of them below, with the objects they name alongside it.

What a real coating leaves behind, and over what range. Reflectance against wavelength for a glass surface of index 1.52 in air, uncoated and with quarter-wave layers of 2 different indices, each a quarter of a wave thick at 550 nm. The ideal index is the geometric mean, 1.2329, and the layer made of it takes the reflectance to zero at the design wavelength exactly. No durable solid has that index: magnesium fluoride at 1.38 is the usual compromise and it leaves 1.26% at the design wavelength against 4.26% bare — a reduction of 3.4× rather than a removal. Both curves rise away from the design wavelength, because the thickness is a quarter of a wave only there, and the useful band is wide but not unlimited: the better coating stays under a quarter of the bare reflectance from 415 to 780 nm. The purple cast of a coated lens is that residual — the ends of the visible reflecting while the middle does not.

The layer that makes a reflection vanish

A wave meeting a step in impedance reflects, and nothing can be done about the step. Put a third medium between the two, a quarter of a wavelength thick and of exactly the intermediate impedance, and the reflection stops existing — not reduced, cancelled.

waves · Impedance
Two ways to weaken a surface. Surface tension is a property of a surface rather than a constant of a liquid, and this shows how far it moves. The steep curve is water with ethanol dissolved in it, against ethanol mole fraction, through nine measured points: two per cent of ethanol takes the tension from 72 to 56.4 mN/m, a fall of 22% for a change of composition small enough to taste and not to see. The initial slope is 837 mN/m per unit of mole fraction, because ethanol collects preferentially at the surface and a little of it covers a great deal of area. The gentle line is pure water against temperature, read on the same horizontal axis as degrees rather than fraction: about 0.15 mN/m per degree, so a difference of ten degrees across a surface is worth about a millinewton per metre. Neither dependence would be interesting if surfaces were uniform. What makes them matter is that a difference in tension across a surface is a force along it, and nothing in the liquid prevents such a difference from existing.

The surface that pulls toward the stronger side

Surface tension is usually treated as a constant of a liquid, and it is not — it depends on temperature and on what is dissolved, and a difference in it along a surface is a force along that surface — which drags the liquid underneath and needs no pressure difference at all.

fluids · Surface tension
The screening that survives to zero frequency. How far a magnetic field gets into copper against how fast it is changing, drawn beside the London depth of a superconductor with a carrier density of 6.0e+28 per cubic metre. The metal's curve falls as one over the square root of the frequency — measured on the drawn curve as -0.5000 against −½ — and it is a straight line on these axes with no bottom: at a hundred hertz the field reaches nine millimetres in, and at zero frequency it reaches all the way through, because a normal metal screens by dissipating and a steady field dissipates nothing. The superconductor's line is flat at 21.7 nanometres. The frequency does not appear in the expression for it, so there is nothing for it to depend on, and the screening is as complete at zero frequency as at any other. The two lines cross at 9.0e+12 hertz, in the far infrared, and above that the ordinary metal is actually the better screen — which is a useful corrective, because a superconductor's advantage is not that it screens harder but that it does not need the field to be changing. What the picture cannot show is where the flat line stops: above the energy gap the pairs break, the superconductor becomes an ordinary metal, and the flat line turns into a sloping one.

The field that is pushed out

A perfect conductor keeps whatever field was inside it when its resistance vanished. A superconductor expels the field either way, and the difference between remembering and expelling is the experiment that showed superconductivity is a state of matter rather than a very good conductor.

electromagnetism · Superconductivity
Echoes from a layer that thins to nothing. Synthetic seismic echoes from a layer between two identical rocks — the top reflecting +R, the base −R — for thicknesses of 0, 5, 10, 15, 20, 25, 30, 40, 50, 60, 75, 100 m, sounded with a 30 Hz pulse in rock of 3000 m/s, whose wavelength in the layer is 100 m. Time runs downward; each trace is one thickness. Thick, the layer gives two separate echoes, one from each face, and its thickness can be read from the time between them. As it thins the two echoes overlap and merge. Near 20 m, about a fifth of a wavelength, they interfere constructively and the combined echo is strongest, 1.45 times one face's echo. Thinner still, the combined echo keeps a fixed shape — the pulse's derivative — and simply weakens in proportion to the thickness; nothing in its timing changes.

The layer too thin to see

A seismic survey sends a pulse of sound into the ground and listens to the echoes from every boundary where the rock changes. A thick layer returns two echoes, one from its top and one from its base, and the time between them gives its thickness. A thin one returns one echo, and below about a quarter of a wavelength the timing says nothing more: every thin layer looks the same, just weaker as it thins. It has not become invisible. It has become unmeasurable in the one way that was being used, and its thickness has moved into the echo's strength and its spectrum.

waves · Impedance
A beaker that empties at a steady rate. The height of liquid helium inside a beaker 1 cm across, held 1 cm above the level of the bath it stands in, against time, as the film carries liquid up the inner wall, over the rim and down into the bath. The film carries a fixed volume per centimetre of rim — 7.5·10⁻⁵ cm³/s at 1.4 K — whatever the difference of levels, so the level falls in a straight line, 180 μm a minute, and the beaker is level with the bath in 56 minutes. At 1.9 K, with less superfluid, it takes 95 minutes; at 2.1 K, 279. Dashed, a flow driven by the difference of levels, like a siphon, starting at the same speed: it slows exponentially as the difference shrinks and never quite finishes. The film's straight line is the signature of a flow set by a critical speed, not by the push.

The film whose thinnest point sets the flow

Leave a beaker of superfluid helium standing in a bath and it empties itself, the liquid creeping up the inside wall as a film eighty atoms thick, over the rim and down the outside. The film itself is nothing special: ordinary liquid helium coats the wall just as thickly. What is special is that it flows without friction, and so its flow is set not by how hard it is pushed but by how fast it can go. The level falls in a straight line rather than slowing as it nears the bath's, and the whole flow is decided at one place, the rim, where the film is thinnest and has to run fastest.

quantum · Superfluidity

Named alongside it

The objects these essays reach for when they reach for this one.

ImpedanceInterferenceWettingAcoustic impedanceAntireflectionBandwidthBoundary conditionBragg mirrorCritical fieldCritical velocityDestructive interferenceDiffusion

All concepts