Illustrated Physics
physics, drawn
Concept

Binomial distribution — where it appears

The probabilities of each possible number of successes in a fixed count of independent trials with the same chance each. Its mean is the count times the chance, its spread grows only as the square root of the count, and it becomes a bell curve when the count is large.

Named by 2 essays across 2 fields — each of them below, with the objects they name alongside it.

Every reaction's free energy has its lowest point inside. An ideal reaction A ⇌ B at 298 K. Across: how far it has gone, from pure A towards pure B. Up: the Gibbs energy of the mixture per mole, relative to pure A. Left, for standard reaction Gibbs energies ΔG° of −4, 0, +4 kJ/mol: the dashed straight lines are what the energy would be if A and B did not mix, and the solid curves add the entropy of mixing them. For ΔG° = −4 kJ/mol the lowest point is at 83.4 per cent B; for ΔG° = 0 kJ/mol the lowest point is at 50.0 per cent B; for ΔG° = +4 kJ/mol the lowest point is at 16.6 per cent B. Right, magnified near pure A, a reaction with ΔG° = +10 kJ/mol, whose straight line climbs from the start and which looks as if it should not proceed at all: its curve first falls, to a minimum of −43 J/mol at 1.74 per cent B, because the mixing term falls infinitely steeply away from a pure end. Each minimum was found by search and sits where the ratio of B to A equals exp(−ΔG°/RT).

The reaction that cannot go all the way

Chemistry speaks of reactions that go to completion and reactions that do not happen, and at equilibrium there are neither. The reason is a logarithm. The free energy of a half-finished reaction contains the entropy of mixing, whose slope is infinite at both pure ends, so every reaction's lowest point lies strictly inside — and the slope of that free energy, the chemical potential, is to particles what temperature is to heat.

thermodynamics · Chemical potential A round uncertainty sheared into a thin one. The uncertainty in the direction of 100 atoms' combined spin, seen along the spin, drawn out to one standard deviation in each direction. Left: the atoms each in an independent superposition — a disk of variance N/4 = 25 in every transverse direction, so a rotation shows only once it moves the spin by √N/2 = 5.0 units. Right: after one-axis twisting, which turns the spin about the vertical axis at a rate proportional to its height, so that the upper half of the disk is pushed one way and the lower half the other (arrows). The disk becomes an ellipse with variances 1.22 and 535, its long axis tilted 12.2° from the horizontal. Its narrow direction, turned to lie along the rotation to be measured, is 12.0 dB quieter than the disk, allowing for the 11.8% the twisting costs in the length of the spin.

The atoms that measure better together

A clock read with a hundred independent atoms locates its phase no better than the scatter of a hundred coin tosses allows, because each atom answers the final question by itself. Let the atoms interact for a moment before they are read and that scatter can be shaped: the round uncertainty of their combined spin is sheared into a thin ellipse, and a phase error invisible against the coin-toss noise becomes four standard deviations wide. The gain grows with the number of atoms, and it is real only if the detector can count atoms nearly one by one.

quantum · Measurement

Named alongside it

The objects these essays reach for when they reach for this one.

Atomic clockBloch sphereChemical equilibriumChemical potentialEntanglementEntropy of mixingEquilibrium constantFree energyLe chateliers principlePartial pressureQuantum projection noiseSpin squeezing

All concepts