Series

Superfluidity — the series

7 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. Two transitions, one shape and one not. The condensate fraction of an ideal Bose gas, 1 − (T/Tc)^3/2, drawn against the superfluid fraction of liquid helium-4, which goes as roughly 1 − (T/Tλ)^5.6. Both reach one at absolute zero and zero at their transition, and in between they disagree everywhere. The ideal calculation says why a transition has to exist; it does not describe the one that does, because its atoms do not interact and helium's do.

    The liquid that will not slow down

    Cool helium below 2.17 kelvin and it starts flowing through gaps no ordinary liquid could enter, climbs out of its own container, and circulates for as long as anyone has been willing to watch. The viscosity is not small. As far as any measurement can tell, it is zero.

    part 1 · quantum
  2. Circulation against how fast the bucket turns. The circulation round the rim of a bucket of radius 1 mm, against the angular velocity it is spun at. An ordinary liquid ends up rotating with the bucket, and its circulation is 2Ω times the area — the straight dashed line, continuous in Ω and with no special value anywhere on it. A superfluid's velocity is the gradient of a phase, so it can carry circulation only in whole units of h/m = 9.969e-8 m²/s. Below 0.256 radians per second it carries none at all: the bucket turns and the liquid does not, which is what Hess and Fairbank measured. Above it the circulation is a staircase of 13 steps, each exactly one quantum high and each 1.59e-2 radians per second wide. The staircase runs below the classical line by the ln(R/a) quanta the threshold costs, a fixed lag: at 102 radians per second the two agree to 0.24 per cent, which is why a rotating superfluid looks like a rotating liquid at any speed a bucket is normally spun at.

    The whirlpool that comes in one size

    Spin a bucket of ordinary liquid and it ends up turning with the bucket. Spin a bucket of superfluid helium slowly and it does not turn at all. Spin it faster and it does not turn either — until a threshold, at which a single line of circulation appears, carrying not some amount but exactly h/m. There is nothing in between, because the velocity is the gradient of a phase and a phase has to come back to itself.

    part 2 · fluids
  3. The height a 1 mK difference lifts helium. The head of liquid that a temperature difference of 1 millikelvin can support across a superleak — a plug fine enough that the normal fluid cannot pass and the superfluid can — against the temperature it is done at. Only the normal component carries entropy, so warming one side makes the superfluid flow toward the warm side until the pressure difference balances, and equilibrium is at ΔP = ρSΔT. The height that supports is SΔT/g, in which the density cancels exactly; computed both ways here the two agree to machine precision. The numbers are the striking part: 2.0 mm at 1.2 K, 4.6 mm at 1.4 K, 9.2 mm at 1.6 K, 19.4 mm at 1.8 K, 46.9 mm at 2 K, from a temperature step a thousand times smaller than anything a hand could feel. Aim a light at the warm side and the liquid does not merely rise but jets out of the tube, which is the fountain effect Allen and Jones found in 1938 and the most direct demonstration that helium II is two fluids rather than one. The entropies used are measured values; everything else on this chart is computed from them.

    The fountain a lamp can drive

    Below two degrees above absolute zero, liquid helium behaves as though it were two fluids occupying the same space — one carrying all the entropy and all the viscosity, the other carrying neither. It is not a metaphor and not a mixture. Shine a light on one side of a fine plug and the liquid jets out of the tube, because a temperature difference of a thousandth of a degree is a pressure of a hundred pascals.

    part 3 · fluids
  4. The speed of a wave that carries no pressure. Second-sound speed against temperature, computed from the two-fluid equations with the normal component treated as a phonon gas — which it is below about six-tenths of a kelvin. The upper line is ordinary sound at 238 m/s, which moves the two components together. The lower curve is the other mode, and at low temperature it sits at 137.4 m/s, which is 238/√3 to three figures: a result with no adjustable constant in it, and the reason to believe the two-fluid model rather than merely to use it. What oscillates in this wave is not the density — the two components move in opposite directions and their sum stays put — but the fraction that is normal, which is a temperature. So a temperature disturbance in helium II propagates, with a speed, a reflection and a resonance, where in every ordinary liquid it diffuses and has none of those. Above a kelvin the rotons take over from the phonons and the measured curve falls to about 20 m/s; the model here is the low-temperature one and it is drawn only where it holds.

    The heat that arrives as a wave

    Two fluids with two velocities give two wave equations, not one. In the first the components move together and the density oscillates, which is ordinary sound. In the second they move oppositely, the density stays put, and what oscillates is the temperature — so a heat pulse in liquid helium has a speed, a front and a reflection.

    part 4 · fluids
  5. Helium's excitations, and the line that decides how fast it can flow. The energy of an elementary excitation in superfluid helium-4 against its momentum, as a smooth fit through published neutron-scattering values: a phonon branch rising at the speed of sound, 238 m/s, a maximum near 13.9 K, and the roton minimum of 8.62 K at 1.92 Å⁻¹. A straight line from the origin has a slope that is a velocity. The steepest line that just touches the spectrum is Landau's critical velocity, 57 m/s, and it touches at 1.98 Å⁻¹, just past the roton minimum. A body moving slower than that cannot make any excitation at all and so cannot lose energy to the liquid; the dashed line is the speed of sound, far above it.

    The speed below which nothing can be made

    An object moving through an ordinary liquid always feels drag, because it can always pass some of its energy to the liquid. In a superfluid there may be nothing it can pass it to. Landau's argument turns the question into geometry: an excitation of momentum p and energy ε can be made only by a body moving faster than ε/p, so a liquid flows without friction below the smallest value of that ratio. For helium the smallest value is not the speed of sound but 57 m/s, set by the dip in its spectrum called the roton — and an ideal gas, with no dip and no sound, has no such speed at all.

    part 5 · quantum
  6. A beaker that empties at a steady rate. The height of liquid helium inside a beaker 1 cm across, held 1 cm above the level of the bath it stands in, against time, as the film carries liquid up the inner wall, over the rim and down into the bath. The film carries a fixed volume per centimetre of rim — 7.5·10⁻⁵ cm³/s at 1.4 K — whatever the difference of levels, so the level falls in a straight line, 180 μm a minute, and the beaker is level with the bath in 56 minutes. At 1.9 K, with less superfluid, it takes 95 minutes; at 2.1 K, 279. Dashed, a flow driven by the difference of levels, like a siphon, starting at the same speed: it slows exponentially as the difference shrinks and never quite finishes. The film's straight line is the signature of a flow set by a critical speed, not by the push.

    The film whose thinnest point sets the flow

    Leave a beaker of superfluid helium standing in a bath and it empties itself, the liquid creeping up the inside wall as a film eighty atoms thick, over the rim and down the outside. The film itself is nothing special: ordinary liquid helium coats the wall just as thickly. What is special is that it flows without friction, and so its flow is set not by how hard it is pushed but by how fast it can go. The level falls in a straight line rather than slowing as it nears the bath's, and the whole flow is decided at one place, the rim, where the film is thinnest and has to run fastest.

    part 6 · quantum
  7. The peak that rises out of a cloud. A slice through the shadow a released cloud of a million atoms casts after it has expanded, the measurement by which condensates are seen, at 1.1, 0.8 and 0.5 times the transition temperature: the thermal atoms, whose spread of speeds sets the cloud's width, give a broad rounded profile; the condensed atoms, all in one state with only the small spread of momenta their trap allowed, give a narrow peak at the centre, drawn here with the shape repulsion between the atoms gives it. Above Tc there is only the broad cloud. At 0.8 Tc a sharp peak stands up from its middle, holding 47 per cent of the atoms; at 0.5 Tc the peak holds 87 per cent and the thermal wings have shrunk. The two-component shape — a narrow peak on a broad base — was the signature that announced the first gaseous condensates in 1995.

    The condensate a trap makes

    A gas of atoms held in a magnetic trap and cooled to a few hundred billionths of a degree does something no gas in a box does at any temperature it can reach: a large share of its atoms falls into the trap's single lowest state, and a sharp peak rises out of the cloud. The reason is counting. The trap's excited states can hold only so many atoms at a given temperature, and the number grows as the cube of the temperature — so below one temperature the atoms run out of room, and every atom that does not fit has only one place to go.

    part 7 · quantum

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