Illustrated Physics
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Series

Superconductivity — the series

9 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. The screening that survives to zero frequency. How far a magnetic field gets into copper against how fast it is changing, drawn beside the London depth of a superconductor with a carrier density of 6.0e+28 per cubic metre. The metal's curve falls as one over the square root of the frequency — measured on the drawn curve as -0.5000 against −½ — and it is a straight line on these axes with no bottom: at a hundred hertz the field reaches nine millimetres in, and at zero frequency it reaches all the way through, because a normal metal screens by dissipating and a steady field dissipates nothing. The superconductor's line is flat at 21.7 nanometres. The frequency does not appear in the expression for it, so there is nothing for it to depend on, and the screening is as complete at zero frequency as at any other. The two lines cross at 9.0e+12 hertz, in the far infrared, and above that the ordinary metal is actually the better screen — which is a useful corrective, because a superconductor's advantage is not that it screens harder but that it does not need the field to be changing. What the picture cannot show is where the flat line stops: above the energy gap the pairs break, the superconductor becomes an ordinary metal, and the flat line turns into a sloping one.

    The field that is pushed out

    A perfect conductor keeps whatever field was inside it when its resistance vanished. A superconductor expels the field either way, and the difference between remembering and expelling is the experiment that showed superconductivity is a state of matter rather than a very good conductor.

    part 1 · electromagnetism
  2. The size of the quantum says what is carrying the current. What the flux quantum would be for each candidate carrier charge, in units of 10⁻¹⁵ webers, against the measured value drawn as a line. A single electron would give 4.1357, a pair 2.0678, a triple 1.3786. The measurement is 2.0678, which picks the pair and excludes the others by a factor of two — not by a few per cent, so no question of experimental accuracy arises. The whole of the argument is that the condensate's wavefunction must come back to itself round the ring, which makes the enclosed flux a multiple of h over the carrier's charge; measuring the multiple therefore measures the charge, without any charge ever being measured. That is how the pairing was established in 1961, four years after it was proposed and by an experiment that looks nothing like a measurement of a charge.

    The two in the flux quantum

    A superconducting ring cannot hold whatever flux is applied to it. It holds a whole number of quanta and drives a current to make up the difference, and the size of that quantum is Planck's constant divided by twice the electron's charge. The factor of two was measured in 1961, four years after somebody predicted that the carriers are pairs — by an experiment in which no charge is measured at all.

    part 2 · electromagnetism
  3. The ring picks a whole number and pays for the difference. The kinetic energy of the screening current in a superconducting ring, against the flux applied from outside, in units of the flux quantum. Each parabola belongs to one winding number — the number of times the condensate's phase turns round the ring, which has to be an integer because the wavefunction has to come back to itself. The ring cannot hold an arbitrary flux, so it holds the nearest whole number of quanta and drives a current to make up the difference; the energy of that current goes as the square of the mismatch, which is what each parabola is. The lowest curve at each applied flux is the state the ring is in, and the winding number changes at exactly the half-integers — 0.50 and 1.50 and 2.50 here. So the measurable properties of the ring are periodic in the applied flux with a period of one quantum, which is 2.0678 × 10⁻¹⁵ webers and is about the flux the Earth's field puts through a square micrometre.

    Two lengths, and which one is longer

    A superconductor has a depth to which a field leaks in and a distance over which superconductivity itself can be built up. Which of the two is larger decides the sign of the energy of a boundary — and therefore whether the material keeps every field out or fills itself with a lattice of holes.

    part 3 · electromagnetism
  4. A current with no voltage, and then a voltage that is a frequency. Current against mean voltage for a Josephson junction shunted by a resistance, in units of its critical current and of the critical current times the resistance. Up to the critical current the junction carries a supercurrent at exactly zero voltage, set by the difference of the two superconductors' phases. Above it a mean voltage appears, growing as R√(I² − Ic²) and approaching the ohmic line at large current; the curve is integrated from the junction equation and checked against that result at three currents. The voltage is not steady. It is a train of pulses, each the phase slipping by one turn, at a frequency of 483.6 GHz per millivolt: for a junction with Ic = 1 mA and R = 1 Ω, one unit of the voltage axis is 1 mV and 484 GHz.

    The voltage that is a frequency

    Two superconductors separated by a barrier a nanometre thick carry a current with no voltage at all, set by the difference of their quantum phases. Push harder and a voltage appears — and a voltage makes that phase difference run, so the current oscillates at 483.6 gigahertz for every millivolt. Shine microwaves on the junction and the voltage locks to exact multiples of the frequency divided by a ratio of fundamental constants, with nothing about the junction in it. That is why a volt is now counted in cycles.

    part 4 · electromagnetism
  5. A pendulum with unequal steps. The potential −EJ cos φ of the junction against its phase, at EJ/EC = 50, with the lowest 4 levels of the circuit drawn across the well between their classical turning points, in units of the charging energy. The transitions are 18.94, 17.79, 16.50, each smaller than the one below it; a harmonic well of the same curvature would space them all at the square root of 8·EJ·EC, 20.00. The spacing shrinks because the cosine is flatter than a parabola away from its bottom, and the shrinking is what lets a microwave pulse tuned to the lowest transition leave the next one alone.

    The circuit that forgets its charge

    A tiny superconducting island joined to its surroundings through a Josephson junction has discrete energy levels, and two of them make a quantum bit. The first such circuits were ruined by stray charges on nearby surfaces, which moved their levels and scrambled any superposition within a nanosecond. The cure was to make the junction's energy fifty times the charging energy. That makes the levels exponentially insensitive to charge while costing only a power-law loss in the unequal spacing that lets one transition be driven alone.

    part 5 · electromagnetism
  6. Rotation is a magnetic field, and a superconductor cancels it. Magnetic fields along the spin axis inside a spinning metal, in units of 2mω/e, as seen by its electrons in the frame turning with it. In that frame the Coriolis force on an electron is exactly the force a magnetic field of 2mω/e would exert, pointing against the spin for a negative charge (Larmor's theorem). A normal metal spun in no field has no real field inside, and its electrons feel the rotation's equivalent field in full. A superconductor will not let its carriers feel any field in their interior — that is the Meissner effect — so it generates a real field of exactly the same size pointing the other way, and the sum vanishes. The real field is the London moment.

    The field a spinning superconductor makes of itself

    Spin a lump of superconductor with no magnet anywhere near it, and a magnetic field appears inside it, pointing along the axis of spin: about eleven trillionths of a tesla for every radian per second, the same in lead, niobium or a copper-oxide ceramic. The field is not left over from anything. In a turning frame the Coriolis force on a moving charge is indistinguishable from a magnetic force, a superconductor will not let its carriers feel any field inside it, and so it makes a real field to cancel the one rotation imitates. The size depends on nothing but the carriers' mass and charge, which makes the field a balance for weighing them — and the one time it was read to a part in a hundred thousand, it gave an answer theory has not matched.

    part 6 · electromagnetism
  7. How a field enters a superconductor that pins it. The magnetic field inside a slab of type-II superconductor, against position across its thickness, as an applied field is raised from zero, in units of the full-penetration field H = Jc a. Each line is the profile at an applied field of 0.5 H, 1.0 H, 1.5 H, 2.0 H. The field enters from both faces as a wedge whose slope is the most current the pinned vortices can carry, Jc; at 0.5 H it reaches halfway to the middle, at H* it just reaches the middle, and beyond that the whole slab carries Jc and the profile rides up with the applied field. A type-I superconductor would show no field inside at all, and a normal metal the applied field everywhere.

    The field a superconductor keeps after all

    A superconductor is famous for throwing magnetic field out, and the experiment that showed it is the one that made superconductivity a state of matter. Most superconductors that are actually used do something closer to the opposite: they let the field in as threads, grip the threads where they are, and keep them when the field is taken away. The result is a slope of field inside the material that is as steep as the grip allows and no steeper, which is all that is needed to explain why such a superconductor has a hysteresis loop, heats up in an alternating field, can hang a magnet underneath itself, and can be made into a magnet stronger than any of iron.

    part 7 · electromagnetism
  8. A current limited by the wire's circumference. The largest supercurrent a wire can carry before the field of its own current destroys superconductivity at its surface, Ic = 2πaHc, against the wire's diameter, for lead, mercury and tin at 1.5 K, on logarithmic axes; dashed, a niobium–titanium wire carrying 3,000 A/mm² in a field of 5 tesla, which grows with the cross-section rather than the circumference. A lead wire 1 mm across carries 192 A — 244 A/mm² — and one 1 cm across only ten times as much, at a tenth of the density. Below 81 micrometres lead carries more than niobium–titanium; above it niobium–titanium wins by a factor that grows with the wire, and it does so in a field of 5 tesla, where lead cannot superconduct at all.

    The current a superconductor stops with its own field

    A superconducting wire has no resistance, so it seems it should carry any current at all. It carries a definite amount and no more, and the amount is set not by the metal's ability to conduct but by the field the current itself makes: when that field at the wire's surface reaches the critical field, superconductivity fails there. The rule makes the largest current proportional to the wire's radius rather than its area, makes a thick wire worse per square millimetre than a thin one, and explains why the first superconducting magnet, wound in 1913, did not work.

    part 8 · electromagnetism
  9. Flux leaving a plate in stripes and spreading into a uniform field. A cross-section through a superconducting plate in the intermediate state near its top surface (below the line), with a normal fraction of 0.40: normal laminae (shaded) each carry the critical field straight up, the superconducting laminae between them carry none. Lengths are in units of the period of the pattern. Above the surface the field lines (solid) are computed from the stray field of the stripes: they fan out from each normal lamina and close up over the superconducting ones, and within about a third of a period the field is uniform at 0.40 of the critical field — the applied field, which is all a distant observer measures. The fanning field stores energy, and it stores more the wider the stripes are, because a wider pattern's non-uniformity reaches further out. That is half of what sets the period.

    The stripes a superconductor makes of a field

    A superconductor expels a magnetic field, but only if the field it pushes aside stays below the critical field everywhere at its surface — and for anything but a long rod held along the field, the field it pushes aside piles up at its edges. A flat plate laid across a field cannot expel any of it. It splits instead into interleaved bands of normal metal carrying exactly the critical field and superconducting metal carrying none, in the proportion flux demands, and the bands have a definite width. Walls between the two cost energy and favour few, broad bands; the field fanning out of the surface favours many narrow ones. The compromise is the geometric mean of the plate's thickness and a microscopic length.

    part 9 · electromagnetism

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