Illustrated Physics
physics, drawn
Series

Rheology — the series

9 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. Four answers to one push. Shear stress against shear rate for four fluids. The straight line through the origin is the Newtonian definition and is the only one of the four for which the word viscosity names a number. The Bingham fluid does not move at all until the stress passes 0.4, which is why toothpaste holds a shape on a brush and why wet concrete can be stood in a heap.

    The fluid that answers back

    For water, stress is proportional to how fast it is sheared, and the constant of proportionality is its viscosity. For paint, blood, ketchup and cornflour in water, it is not — and once the proportionality goes, so does the idea that viscosity is a number a substance has.

    part 1 · fluids
  2. Solid and liquid are answers about a duration. The relaxation time of seven materials, on a logarithmic axis spanning 39 decades, against the length of one observation. A material behaves as a solid when its relaxation time is longer than the observation and as a liquid when it is shorter, so the vertical line is what decides which — and it is a property of the observer. At 1 s, 4 of these are solids. Move the line six decades to the right and pitch joins the liquids; move it far enough left and water is a glass, which is not a figure of speech but what a picosecond pulse measures.

    The liquid that remembers

    Pitch shatters like glass under a hammer and flows through a funnel over a decade. Neither behaviour is the true one. What decides which a substance shows is not the substance but the length of the observation, and the ratio between the two has a name and a number.

    part 2 · fluids
  3. The thickness a paste can hold on a slope. The greatest thickness a yield-stress fluid can rest at without flowing, against the angle of the surface it is resting on, on a logarithmic vertical axis, for four materials. A layer of thickness h puts a shear stress ρgh sin α on its own base; it stays put while that is below the yield stress and flows when it is not, so the critical thickness is τ_y divided by ρg sin α and it depends on nothing else — not on the viscosity, not on how long it is left, not on how it was put there. On a vertical wall the numbers are 1.4 mm of ketchup, 9.2 mm of mayonnaise, 15.7 mm of toothpaste, 15.1 mm of basaltic lava, which is why toothpaste stays on a brush and ketchup does not stay on a plate held up. Read the other way it is a measurement: a lava flow that came to rest 3 centimetres thick on a 30° slope had a yield stress of about 400 pascals, and that is how the rheology of a flow nobody was standing next to is recovered from its shape a thousand years later. The model stops where the layer is thin enough for surface tension to matter and where the material's yield stress depends on how long it has been left alone, which for most of these it does.

    The paste that holds up its own hill

    Toothpaste stands on a brush and ketchup does not stand on a plate, and the difference is a single number with the units of a pressure. Below it a material does not flow slowly — it does not flow. That threshold turns a rheological property into a length, and the length is why a lava flow's thickness says what the lava was made of.

    part 3 · fluids
  4. The same liquid climbs a thin rod and is thrown off a thick one. The height of the free surface against distance from the axis, for rods of 10.0, 25.0, 60.0 millimetres radius turning at one revolution a second in the same polymer solution, with the Newtonian answer dashed. Two effects compete and they fall off at different rates: a hoop tension along the curved streamlines pulls the fluid inward and lifts it, falling as the fourth power of the distance, while the centrifugal term pushes it outward and lowers it, falling as the second. Near a thin rod the fourth power wins and the liquid climbs — 2.21 millimetres at the thinnest. Beyond a radius of 34.64 millimetres it does not, and the same fluid at the same speed is thrown outward exactly as water would be. The changeover is a property of the fluid and the rod together, so a demonstration that works on a glass stirring rod fails on a spoon handle.

    The liquid that climbs the rod

    Stir water with a rod and it is flung outward, leaving a dip at the centre. Stir a polymer solution and it climbs the rod instead. Nothing about the viscosity can produce that, however large it is made — what produces it is a second stress that appears in shear and has no Newtonian counterpart at all, growing as the square of the rate where the familiar one grows in proportion.

    part 4 · fluids
  5. Above a half, the chains stop letting go. The extensional viscosity of a dilute polymer solution, as a multiple of its zero-shear viscosity, against the accumulated stretch (Hencky strain, the stretch rate times the time), on a logarithmic axis, for stretch rates whose product with the relaxation time is 0.1, 0.4, 0.6, 1. The polymer carries 90 per cent of the viscosity. Dashed curves are the Oldroyd-B dumbbell, integrated from its conformation equation and matching its closed form; solid curves are the same chains with a finite length, FENE-P with L² = 400. At 0.1 the Oldroyd-B viscosity reaches 3.37 and the finite chain 3.37 by a strain of 6; at 0.4 the Oldroyd-B viscosity reaches 9.49 and the finite chain 9.25 by a strain of 6; at 0.6 the Oldroyd-B viscosity reaches 58 and the finite chain 49 by a strain of 6; at 1 the Oldroyd-B viscosity reaches 725 and the finite chain 329 by a strain of 6. Below one half the viscosity settles at a few times the shear value. Above it the Oldroyd-B chain stretches without limit and its resistance grows exponentially, while the finite chain grows until it is nearly fully extended and then stops, hundreds of times higher than it began.

    The stretch a chain cannot outrun

    A Newtonian liquid pulled into a thread resists exactly three times as hard as it resists being sheared, whatever it is made of. A polymer solution resists three times as hard only until the stretch rate passes one over twice its relaxation time. Past that, its chains can no longer recoil as fast as they are pulled apart, and the same liquid that is barely thicker than water in a stirred beaker becomes hundreds of times stiffer in a thread.

    part 5 · fluids
  6. Flow curves that bend back, and one that stops. Shear stress against shear rate, both on logarithmic axes, for volume fractions 0.5, 0.55, 0.565, 0.575, 0.6, from the same model: stress in units of σ, rate in units of σ over the liquid's viscosity. Below φ = 0.569 every curve rises steadily — the suspension thickens but continuously. Above it and below the frictional jamming point 0.58 the curve bends back into an S: over a range of stress, more stress gives less flow, and a suspension driven at a fixed rate must jump between branches. At φ = 0.6 the curve returns to zero rate at 2.47 σ*: pushed that hard, the suspension stops flowing altogether and holds the stress like a solid.

    The suspension that seizes when pushed hard

    Cornflour stirred into half its volume of water runs off a spoon like cream, and a fist driven into it bounces off as if it had hit a floor. The particles have not changed and neither has the water. What changes, above a threshold stress, is the kind of contact between neighbouring grains: lubricated, they slide past one another and the suspension can pack to 64 per cent before it locks; pressed into frictional contact, they lock at 58. A suspension sitting between those two numbers is a liquid when handled gently and a solid when handled hard.

    part 6 · fluids
  7. The same paste stopping or running, according to the push. A thixotropic paste, sheared hard and then held under a constant stress: its viscosity against time, on a logarithmic axis, for stresses of 1.5, 1.8, 2.0, 2.4 Pa. Its structure builds at rest and is broken by flow, and the model's critical stress is 1.89 Pa. Below it the paste's viscosity climbs without limit: it slows, its structure builds faster than the slowing flow can break it, and it creeps to a stop, its viscosity growing in the end as the 1.5 power of time. Above it the viscosity falls: it speeds up, breaks its structure faster, and runs at a steady rate. After a thousand seconds the viscosities stand at 514.1, 238.3, 2.0, 1.5 Pa s: stresses a few per cent apart have gone opposite ways — a bifurcation, not a smooth change — and the paste hesitates longest when the stress is closest to the critical value.

    The paste that forgets it was stirred

    A jar of clay slurry left on a shelf sets like a jelly; shaken, it pours. That is thixotropy, and the tempting description — its viscosity falls when it is stirred — misses what makes it strange. A thixotropic paste has no viscosity at a given rate of stirring until it has been told how long it has been stirring, and under a steady push it cannot settle on a slow flow at all. Push slightly less than a critical stress and it creeps to a halt; push slightly more and it runs. Between the two there is nothing, and a paste made to flow slowly splits into a layer that flows and a layer that does not.

    part 7 · fluids
  8. Blood's viscosity, measured in tubes of different sizes. The viscosity of blood at a haematocrit of 45 per cent, as a multiple of the plasma's, measured in glass tubes of each diameter (the fit of Pries and colleagues to many experiments), against the diameter on a logarithmic axis, with the two-layer model of a core inside a cell-free sleeve 2.5 μm thick, the core 4 times as viscous as plasma (dashed). In wide tubes blood is 3.20 times as viscous as plasma. From about half a millimetre down it gets steadily thinner, to 1.25 times at 6.8 μm — about the size of one red cell — and then climbs steeply, to 5.5 at 3 μm, where cells must fold to get through at all. Which viscosity blood has depends on the tube it is in.

    The viscosity that belongs to the tube

    Measure the viscosity of blood in a wide glass tube and it is about three times that of the plasma it is made from. Measure it in a tube a tenth of a millimetre across and it is lower; in one a hundredth of a millimetre across, lower still, barely more than plasma's. Then, below about six micrometres, it shoots up. The blood has not changed. The red cells push themselves away from the wall and leave a sleeve of plain plasma a few micrometres thick for the rest to slide in, and in a narrow tube that sleeve is a large part of the flow. A viscosity that depends on the pipe is no longer a property of the fluid alone.

    part 8 · fluids
  9. The force to pull a foot out of packed sand. The suction that resists pulling a foot (a sole of 250 cm², 10 cm long) straight up out of sand, as water is drawn through the sand into the space the foot leaves — Darcy's law with a Kozeny–Carman permeability — against the pulling speed, on logarithmic axes, for compacted sand (fraction 0.6) of three grain sizes and for loose sand (0.41) of 0.1 mm; the dotted line is a 70 kg person's weight. The force is proportional to the speed and inversely to the square of the grain size. Pulled at a centimetre a second from compacted 0.1 mm sand, a foot resists with 2.5 kN, 4 times the person's weight; the speed at which the suction equals that weight is 2.71 mm/s. In the loose sand before it compacted, the same pull would need 15 per cent of the force; with clay filling the pores of the compacted sand, as in natural quicksand, a thousand times more, and the speed a body's weight can pull at falls to microns a second.

    The sand that lets a body in and will not let it out

    Quicksand cannot swallow anyone: liquefied, it is nearly twice as dense as water, and a person in it floats with their chest clear. What makes it dangerous is the opposite asymmetry. Going in is easy, because a step breaks the gel holding the grains apart and the sand turns liquid. Coming out is hard, because the sand settles and packs around whatever sank, and a trapped foot can only rise as fast as water can seep through the packed grains to fill the space it leaves. Pulling harder barely helps; letting water in does.

    part 9 · fluids

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