Illustrated Physics
physics, drawn
Series

Exclusion — the series

7 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. The energy ladder of a box. The first 6 energy levels of a box, drawn to scale in E₁, at 1.0, 4.0, 9.0, 16.0, 25.0, 36.0. The levels spread apart as the square of n, so a box's spectrum has no top. The arrow marks a transition: 4 to 3 releases 7.000 E₁.

    No two in the same state, and why matter has volume

    Nothing in the energy levels of an atom says how many electrons may occupy each one. The answer is one per state, it is not derived from any force, and it is the reason a table holds a cup up.

    part 1 · quantum
  2. How much of copper's electron sea a temperature can reach. The probability that a state of a given energy is occupied, in copper, at 4 temperatures, with energy measured in units of the Fermi energy — 7.04 eV here. At absolute zero the curve is a step: every state below the ceiling is full and every state above it is empty. Raising the temperature rounds the step, and rounds it over a range of about kT, which is the whole point — at room temperature kT is 0.0259 eV against a ceiling of 7.04 eV, so the rounding is 1.6 per cent of the way down the sea and everything deeper is untouched. An electron in the deep is not held there by a force; it simply has nowhere to go, because every state it could be promoted to is occupied. at 0 K the step is spread over 0.00 per cent of E_F, at 300 K the step is spread over 1.61 per cent of E_F, at 3000 K the step is spread over 16.13 per cent of E_F, at 20000 K the step is spread over 107.52 per cent of E_F.

    The pressure that is not a temperature

    Copper's conduction electrons are at a temperature of eighty thousand kelvin, in a wire that is at room temperature. That is not a figure of speech, it is what the exclusion principle does to a mole of particles, and it explains the largest unexplained number in the theory of metals.

    part 2 · quantum
  3. The hole that holds exactly one particle. How likely a second particle is to be found a distance away from a first, relative to a gas with no correlation at all, for three cases that differ in nothing but the symmetry of the state under swapping the two labels. There is no interaction anywhere in this calculation: no Coulomb term, no potential, no force. Distinguishable particles give a flat line, which is what no interaction ought to give. Identical fermions dig a hole that reaches exactly zero at zero separation and fills back in over about a wavelength. Identical bosons do the opposite and pile up to twice the density. Integrating the fermion hole gives 0.9992 particles missing from around each one — exactly one, and the sum rule holds at any density, because raising the density narrows the hole in exact proportion. That is what makes the effect worth a name of its own. It is often called an exchange force and it is not a force: nothing carries momentum between the particles, and no term in the energy is proportional to a distance. It is a statement about which states exist. What follows from it is most of chemistry — the reason two atoms with filled shells repel, the reason a metal's electrons cost so much less Coulomb energy than a random arrangement would, and the reason matter takes up room.

    The force with no force in it

    Two identical fermions keep apart and two identical bosons crowd together, and neither is being pushed. The Hamiltonian contains no interaction at all: what produces the hole and the pile is which many-particle states exist, and the hole it digs around each electron holds exactly one particle at any density whatever.

    part 3 · quantum
  4. The triangle of collisions that survive. Every collision of a particle ε above a filled Fermi sea with a partner from the sea, at zero temperature: the partner's energy across, one product's energy up, both from the Fermi level, the other product's fixed by energy conservation. Without exclusion every point in the plotted square would be an allowed collision. With it, the partner must come from below the Fermi level, and both products must land above it: the partner no deeper than ε below, the first product above zero, the second product above zero too. What survives is the shaded triangle, whose area is half of ε squared, and the collision rate is proportional to it. Halve the particle's excess energy and the triangle shrinks to a quarter; at the Fermi level itself it vanishes, and a particle there cannot scatter at all.

    The collisions the exclusion principle forbids

    A copper wire holds one free electron per atom, packed a quarter of a nanometre apart and repelling one another with the full Coulomb force. It seems impossible that an electron could travel any distance through that crowd without colliding. It travels micrometres — thousands of atoms — before another electron deflects it. The collisions are not weak. They are forbidden: to collide, both electrons need empty states to move into, and in a sea filled to the brim almost none exist. The same rule makes cold helium-3 thicken as the square of how cold it gets.

    part 4 · quantum
  5. Three identical quarks in one state, and the label that rescues them. The Δ⁺⁺ particle, mass 1,232 MeV and charge +2, drawn as the quark model describes it: three up quarks, all in the lowest orbital state, all with their spins pointing the same way, giving spin 3/2. Left: with nothing else to tell them apart, the state is unchanged by swapping any two quarks — symmetric in where they are, in their spins and in their flavour — which the exclusion principle forbids for identical fermions. Right: give each quark a label that takes three values, and put the three in the one combination of the three values that changes sign under every swap. The whole state is then antisymmetric, as it must be, and the particle is allowed. The label is called colour, and three is the smallest number of values that can do this for three quarks.

    The label three identical quarks forced

    In 1964 the quark model had one embarrassment it could not explain away. A particle called the Δ⁺⁺, well measured and entirely ordinary, had to be three identical up quarks in the same state with their spins pointing the same way — which the exclusion principle forbids outright. The way out was to give quarks a hidden property that takes three values, so that the three could be different after all. Nobody could see the property, and for years it looked like a bookkeeping trick. Then three independent measurements counted it, and every one came out at three. The exclusion principle, which keeps electrons in shells, had predicted the colour of the strong force.

    part 5 · quantum
  6. Which atoms in a Fermi sea are allowed to take a photon's kick. A slice through the occupied momentum states of a gas of identical fermions at zero temperature — a filled disc whose radius is the Fermi momentum — with each state marked by whether it can absorb a recoil of 0.8 of the Fermi momentum to the right, the kick a scattered photon gives. A state can scatter only if its kicked momentum lands outside the sea, in an empty state. The kicked sea is the second circle; the atoms in the overlap of the two (grey) land on occupied states and cannot scatter, and only those in the crescent (blue) can. In this slice 50 per cent of the states are allowed; over the whole sphere the allowed share is S(q) = 3q/4 − q³/16 = 0.568. A kick larger than the sea's diameter, twice the Fermi momentum, is never blocked, which is why the effect needs a sea whose Fermi momentum is comparable with the photon's.

    The light a full sea will not scatter

    An atom that scatters a photon recoils, and the recoil has to put it into a new state of motion. In a cold, dense gas of identical fermions most of the states it could recoil into are already taken, and the exclusion principle forbids the scattering outright. Nothing about the atom has changed — not its electrons, not its transition, not its cross-section — yet the gas becomes dimmer than the same number of atoms scattered one at a time. The effect was predicted in the 1990s and seen in 2021, and it turns transparency into a measurement of how full a quantum gas is.

    part 6 · quantum
  7. The cloud that stops shrinking. The rms size of a cloud of 10⁵ ideal atoms in a harmonic trap, in units of the Fermi radius, against temperature in units of the Fermi temperature, for fermions, for bosons and for a classical gas. The classical cloud shrinks as the square root of half the temperature ratio, all the way to nothing. The bosons follow it down to their condensation temperature, 0.52 of the Fermi temperature, and then collapse into the trap's ground state, whose rms size is 0.054 Fermi radii. The fermions part from the classical line near the Fermi temperature and level off at one over the square root of eight, 0.354 of the Fermi radius: at a quarter of the Fermi temperature they are 1.17 times the classical size, and cooling further barely changes them. Mixed together in one trap, as lithium-7 and lithium-6 were in 2001, the two clouds start the same size and end 6.5 times apart in width for ideal atoms of these numbers — further still in volume. The fermions are held up by nothing but the rule that no two of them may share a state.

    The cloud that stops shrinking

    Two kinds of lithium atom, cooled together in one magnetic trap to a few hundred billionths of a degree, start as clouds of the same size and end very differently. The lithium-7 atoms, which are bosons, shrink with the temperature and then collapse into a condensate. The lithium-6 atoms, which are fermions, stop shrinking at about a quarter of their Fermi temperature and refuse to get any smaller, however much colder they become. Nothing pushes them apart but the rule that no two identical fermions may share a state. The photographs taken in 2001 were the first time Fermi pressure — the pressure that holds up white dwarfs — was seen as a picture.

    part 7 · quantum

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