Dispersion — the series
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The angle the rainbow has to be, and why nobody chose it
A rainbow is at forty-two degrees because a function has a minimum there. Nothing about water, light or weather picks the number — it falls out of running Snell's law three times through a sphere.
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Two glasses that cancel a derivative
A single lens focuses blue light closer than red, and the difference ruins the image. Cementing a second lens of another glass behind it fixes the fault at two wavelengths and at no others, because the condition sets a slope to zero rather than a value.
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The wavelength a fibre does not smear
Fused silica's index has a second derivative that passes through zero at 1,273 nanometres, and that is not a design choice — it is where the ultraviolet and infrared absorptions balance. A pulse sent at that wavelength arrives the shape it left. A pulse at the wavelength of least loss arrives 1,800 picoseconds wider after a hundred kilometres.
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The ring at twenty-two degrees
A halo round the sun is a caustic in orientation rather than in space. Most of the ice crystals in a cirrus cloud send light nowhere in particular; the ones near minimum deviation all send it to nearly the same angle, because a minimum is flat — and the angle they pick has a red inner edge, which is the reverse of a rainbow.
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The delay that is a random variable
A fibre's core is very slightly elliptical, so its two polarisations travel at very slightly different speeds — and the ellipse turns, at random, every hundred metres or so. The delays of the pieces do not add. They random-walk, so the total grows as the square root of the length, follows the same distribution as the speeds of gas molecules, differs from one wavelength to the next, and on any particular day may be three times its average.