Dispersion — the series
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The angle the rainbow has to be, and why nobody chose it
A rainbow is at forty-two degrees because a function has a minimum there. Nothing about water, light or weather picks the number — it falls out of running Snell's law three times through a sphere.
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Two glasses that cancel a derivative
A single lens focuses blue light closer than red, and the difference ruins the image. Cementing a second lens of another glass behind it fixes the fault at two wavelengths and at no others, because the condition sets a slope to zero rather than a value.
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The wavelength a fibre does not smear
Fused silica's index has a second derivative that passes through zero at 1,273 nanometres, and that is not a design choice — it is where the ultraviolet and infrared absorptions balance. A pulse sent at that wavelength arrives the shape it left. A pulse at the wavelength of least loss arrives 1,800 picoseconds wider after a hundred kilometres.
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The ring at twenty-two degrees
A halo round the sun is a caustic in orientation rather than in space. Most of the ice crystals in a cirrus cloud send light nowhere in particular; the ones near minimum deviation all send it to nearly the same angle, because a minimum is flat — and the angle they pick has a red inner edge, which is the reverse of a rainbow.
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The delay that is a random variable
A fibre's core is very slightly elliptical, so its two polarisations travel at very slightly different speeds — and the ellipse turns, at random, every hundred metres or so. The delays of the pieces do not add. They random-walk, so the total grows as the square root of the length, follows the same distribution as the speeds of gas molecules, differs from one wavelength to the next, and on any particular day may be three times its average.
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The dispersion made of angles
Glass delays blue light more than red, so a short pulse that passes through glass comes out stretched with its red end first. At the wavelengths where most short-pulse lasers work, no transparent glass does the opposite. Two diffraction gratings do it with no material at all. The first spreads the colours in angle, the second turns them back parallel, and in between the red has travelled the longer road. A spread in angle, however it is made, always adds this kind of dispersion, of the sign glass cannot give. It is how every high-power ultrafast laser squeezes its pulse back after amplifying it.
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The colour at which glass disappears
Lower a glass rod into an oil of the same refractive index and it vanishes, except for a faint coloured outline. The outline is the clue. Glass and oil disperse light differently, so their indices can agree at only one wavelength; at every other the glass is still there, bending and scattering a little. Grind the glass to powder and pack it in the oil, and the mixture is clear at that one wavelength and opaque at the rest — a colour filter made of nothing but two transparent materials, whose colour moves by a whole hue for a few degrees of warming.
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The hooks that weigh an absorption line
A strong absorption line is black at its centre, and how black it is says almost nothing about how many atoms made it — double them and the line hardly darkens. The atoms are still there, and they still bend light: on either side of the line, where the vapour is transparent, its refractive index rises and falls by an amount proportional to their number. In 1912 Dmitry Rozhdestvensky found a way to read that index straight off a photograph. Interference fringes passed through a spectrograph curl into hooks beside the line, and the distance between the hooks, squared, counts the atoms — whatever the line's shape and however saturated its core.
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The absorption measured with a stopwatch
The usual way to measure how much light a gas absorbs is to compare a beam before and after, and a very weak absorption vanishes in the flicker of the lamp. Trap a pulse between two excellent mirrors, and it bounces for ten kilometres inside a tube a metre long, leaking out a little at each bounce. How fast that leak dies measures the gas, and how bright the pulse began does not matter at all. A brightness measurement has become a measurement of time.