Illustrated Physics
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Series

Decay — the series

5 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. Decay, and the ensemble it is a property of. 400 nuclei followed for 4 half-lives. The smooth curve is the exponential; the stepped traces are 3 independent runs in which every nucleus was given its own decay time and told nothing about the others. The number surviving halves at each dashed line — 200, 100, 50, 25 — and it halves again over the next interval regardless of how long the sample has already been sitting there, which is the property no ordinary clock has. The traces wander further from the curve as the numbers get small: at the end only about 25 are left and the scatter is a visible fraction of that.

    A nucleus with no clock

    A half-life is a precise number and no individual nucleus has one. Each has the same chance of decaying in the next second as it had on the day it formed, and the exponential curve is a property of the population rather than of any member of it.

    part 1 · quantum
  2. Flat, then exponential, then a power law. Survival probability against time in lifetimes, both logarithmic, for a resonance 20 linewidths above the bottom of its band and 400 below the top. The straight dashed line is exp(−Γt), and the computed curve sits on it through the middle — a fitted rate of 0.9998 per lifetime between one and eight — and leaves it at both ends. Below 1.57e-2 lifetimes the curve is flat, falling as (t/τ_z)² with τ_z = 0.1253 lifetimes; beyond 22.6 lifetimes it is an inverse square, which any exponential eventually loses to. Both departures are forced: the head by the state being normalisable and the tail by the band having a bottom.

    The exponential that is only true in the middle

    A decay law is not an assumption about nuclei; it is the Fourier transform of an energy distribution. Do that transform honestly and the exponential fails at both ends — flat at the start, because the state is normalisable, and an inverse square at the end, because no system has states of arbitrarily negative energy. Neither departure is a correction that could be made small.

    part 2 · quantum
  3. A line is what two bodies give. The electron energy spectrum of tritium, against the vertical line a two-body decay would produce. A nucleus emitting one particle has no choice about how to share the energy: momentum conservation fixes it, and every electron comes out at the same energy. The observed spectrum is a continuum running from zero to the full available energy, with a mean at 0.31 of the endpoint. The shape is a count of the ways the energy can be divided between an electron and something else, and the something else was proposed for no other reason than that the shape requires one.

    The energy that did not all arrive

    A nucleus emitting one particle has no choice about the energy it comes out with — momentum conservation fixes it, and the spectrum is a line. Beta decay gives a continuum instead, from zero to the full available energy, and the shape of that continuum is a count of the ways the energy can be shared. Counting it required a third body nobody had seen, and the way the count approaches its endpoint is still the best place to weigh one.

    part 3 · quantum
  4. Everything in the chain decaying at the parent's rate. The activity of each member of ²³⁸U → ²³⁴Th → ²³⁴Pa, relative to the parent's, against time in days. The parent's half-life is far the longest, so its activity is effectively constant over the range drawn while each daughter rises to meet it. Once they have, every member of the chain is decaying at exactly the same rate — secular equilibrium, checked here to one per cent off the integrated solution — because each is being made as fast as it is disappearing. The amounts are not equal at all: the abundance of each member sits in the ratio of its half-life to the parent's, which for radium in uranium is one part in three million and is why radium had to be extracted from tonnes of ore.

    The chain that runs at its slowest member's rate

    Put decays in series and something happens that no single decay does. The population settles where every member is being made exactly as fast as it disappears, so every activity in the chain is equal — while the amounts differ by twelve orders of magnitude, in the ratio of the half-lives. A gram of uranium contains a third of a microgram of radium and two hundred million million million atoms fewer of radon, and both numbers are read off a list of half-lives.

    part 4 · quantum
  5. The half-life that depends on the electrons. Half-lives of 3 nuclides as neutral atoms and as bare nuclei, measured at a heavy-ion storage ring where fully stripped ions can be kept circulating for months. The changes are not corrections. ¹⁸⁷Re goes from 41.6 billion years to 32.9 — a factor of 1.26 billion — because a beta decay whose available energy is only 2.5 keV cannot put an electron into the continuum but can put one into an empty K orbital, and stripping the atom opens that channel. ¹⁶³Dy is stable as an atom and decays in 47 days as a bare nucleus, for the same reason. The rate is a property of the nucleus and of what surrounds it, and the rung below this one says otherwise.

    The half-life that chemistry can change

    The first rung of this ladder said a nucleus has no clock and that nothing outside it touches the rate. That is very nearly true and it is not exactly true. Electron capture takes an electron from the nucleus's own position, so its rate is proportional to how many electrons are there — which is chemistry, worth a per cent. And a nucleus stripped of every electron can gain a decay channel it did not have: rhenium-187 goes from forty-two billion years to thirty-three.

    part 5 · quantum

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