Illustrated Physics
physics, drawn
Series

Blackbody — the series

4 essays on one idea, from the one that introduces it to the one that assumes the rest.
  1. The blackbody spectrum, against what classical physics predicted. Spectral exitance against wavelength for a blackbody at 3000, 4000, 5000 kelvin, in kilowatts per square metre per nanometre. Each curve peaks at the wavelength Wien's displacement law gives — 966 nm at 3000 K, 724 nm at 4000 K, 580 nm at 5000 K — and falls to nothing at short wavelengths.

    The curve that would not come down

    Classical physics predicted that a warm object radiates infinite power at short wavelengths. Every step of the derivation was correct, the prediction was absurd, and closing the gap required assuming that energy comes in lumps.

    part 1 · quantum
  2. What a thermal camera reads off a shiny surface. The temperature a camera calibrated for a black body reports, against the emissivity of the surface it is pointed at, for surfaces truly at 323 K, 373 K, 473 K in a room at 293 K. Every curve begins at the true temperature when the emissivity is one and ends at the room's temperature when it is zero, because a surface that emits nothing reflects everything and the camera is then looking at the room. polished aluminium at 0.05 reads 312 K; stainless steel, oxidised at 0.8 reads 451 K; matt black paint at 0.95 reads 468 K; human skin at 0.98 reads 471 K for a surface truly at 473 K. That is not a fault in the instrument. It follows from Kirchhoff's law — a poor emitter is a poor absorber and therefore a good reflector — so the shortfall in a shiny surface's own glow is made up almost exactly by whatever is reflected in it, and no measurement of the light leaving a surface can separate the two without knowing the emissivity in advance.

    The glow that says nothing about the surface

    A thermal camera pointed at a saucepan of boiling water reads a hundred degrees. Pointed at a polished aluminium block at the same temperature it reads about twenty-five, and the instrument is working perfectly. What it is measuring is emissivity as much as temperature — and a surface's emissivity is forced to equal its absorptivity, at every wavelength and every angle, by an argument with no physics of matter in it at all.

    part 2 · thermodynamics
  3. Energy, pressure and entropy of a gas nobody counted. The energy density, pressure and entropy density of blackbody radiation against temperature, on logarithmic axes, together with the pressure a monatomic gas of the same energy density would have. Every curve is a power of the temperature — the fourth for energy and pressure, the third for entropy — because the only length in the problem is the thermal wavelength and the only energy is kT. The pressure is exactly a third of the energy density, where an ordinary gas's is two thirds, a factor of 2: a photon carries momentum E/c and a slow molecule carries √(2mE), and that difference is the whole of it. Some values: at room temperature the radiation pressure is 1.86e-6 pascals, which is a ten thousand millionth of an atmosphere; at 1e+7 kelvin it is 2.52e+12, which is where radiation rather than matter holds a star up.

    The gas that nobody counted

    A box of gas holds however many molecules were put in it. A box of radiation holds however many photons the temperature says, because the walls make and destroy them until the free energy is least — and one dropped assumption changes every result. The pressure becomes a third of the energy density instead of two thirds, the entropy goes as the cube of the temperature, and the adiabatic index comes out at exactly four thirds.

    part 3 · thermodynamics
  4. The temperature a planet ought to be. Each body's measured surface temperature against the temperature at which it would radiate away exactly the sunlight it absorbs — computed from two numbers, the sunlight reaching it and the fraction it reflects, with no other property of the body used. Points on the diagonal are bodies the one-line argument gets right. the Moon: balance 270 K, surface 250 K, −20 K with no atmosphere; Mercury: balance 433 K, surface 340 K, −93 K with no atmosphere; Mars: balance 210 K, surface 210 K, +0 K; Earth: balance 255 K, surface 288 K, +33 K; Venus: balance 227 K, surface 737 K, +510 K. The airless bodies fall below the line rather than on it, and the reason is the fourth power: a surface running from noon heat to night cold radiates like its hottest parts and averages like its coldest, so a mean thermometer reading is lower than the temperature that matches the emitted flux. Mars, whose atmosphere is thin and whose surface is nearly isothermal by comparison, sits on the line. Everything with a substantial atmosphere sits above it, by tens of kelvin on Earth and hundreds on Venus, and always in the same direction. Nothing here explains why. What the figure fixes is the size and the sign of what has to be explained.

    The height a planet is seen from

    A body in sunlight settles where it radiates away what it absorbs, and that takes two numbers and one line of arithmetic. It gets the Moon right and Earth wrong by thirty-three kelvin. The correction is not that the atmosphere traps heat but that it moves the level space sees the planet from, and the rest is done by a lapse rate that is not a radiative quantity at all.

    part 4 · thermodynamics

All series