Ways to arrange 10 coins
At its defaults it draws ways to arrange 10 coins. The number of distinct arrangements giving each number of heads, for 10 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
microstates is one function in lib/figures/thermal.js —
cycles, distributions and the statistics underneath them. Everything below came out
of it during this build, at parameters taken from the essays rather than invented for this
page. A figure here is the figure a reader meets in an essay, and if the generator changes,
this page changes with it.
At its defaults
Drawn even though every essay passes options, because a default nothing exercises is a trap for the next essay to call this with none — which has happened here twice.
The number of distinct arrangements giving each number of heads, for 10 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
Ways to arrange 10 coins
The options are the ones Entropy is a count, and the arrow of time is arithmetic passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The number of distinct arrangements giving each number of heads, for 10 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
Ways to arrange 4 coins
The options are the ones Entropy is a count, and the arrow of time is arithmetic passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The number of distinct arrangements giving each number of heads, for 4 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
Ways to arrange 20 coins
The options are the ones Entropy is a count, and the arrow of time is arithmetic passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The number of distinct arrangements giving each number of heads, for 20 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
Ways to arrange 20 coins
The options are the ones Entropy is a count, and the arrow of time is arithmetic passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The number of distinct arrangements giving each number of heads, for 20 coins. Every individual arrangement is equally likely; the middle wins because there are more ways to reach it.
Whether the entropy doubles when the gas does
The options are the ones Entropy is a count, and the arrow of time is arithmetic passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
Entropy per particle against the number of particles, at fixed density and temperature, counted two ways. The upper line counts arrangements as though every particle carried a label, so that swapping two of them gives a different arrangement; its entropy per particle grows without limit as the sample grows, which no thermodynamic quantity may do — two identical flasks joined together would then have more than twice the entropy of one, and opening a tap between them would produce entropy from nothing. The lower line divides the count by the number of permutations of the particles, and its entropy per particle is flat to 0.0310 across a factor of 40 in size, and what is left of the drift is the leading Stirling correction, ln(2πN)/2N, which is falling toward nothing as the sample grows and is already invisible at any number of particles a flask contains. That division is the whole repair, it is worth exactly one factorial, and it says something physical: two arrangements differing only by which particle is where are not two arrangements. Nothing in classical mechanics requires that, and it had to be put in by hand for forty years before quantum mechanics said why.
What checks it
physicscheck asserts something about microstates that
could fail — it draws it and measures the result against a value reached some other
way.
Across the library: 100 interrogated, 2 exercised only, 1 untouched, of 103. Read out of the gate's source by the gate's own two patterns — and the gate's last claim fails the build if that read disagrees with what it was handed while running.
Where it is called
Changing this generator changes every figure on this list. That is what makes the list worth publishing rather than keeping in a check script.
Entropy is a count, and the arrow of time is arithmetic
Nothing in mechanics prefers a direction. Entropy is not a force pushing things toward disorder — it is the observation that some outcomes have vastly more ways of happening than others.
ThermodynamicsMixing what is already mixed
Let two different gases into each other's halves of a box and the entropy rises by a fixed amount that contains nothing about either gas. Do it with the same gas on both sides and it rises by nothing. Make the gases more and more alike and the answer does not converge — it jumps.
ThermodynamicsThe age a cooling Earth gives
In 1862 William Thomson, later Lord Kelvin, took a thermometer reading from the bottom of a mine and a piece of mathematics from Fourier and computed the age of the Earth: about a hundred million years. Geologists, needing far longer, had no physics with which to reply. The arithmetic was right. The usual story blames radioactivity for overturning it, but half the heat is not radioactive, and the error lay in assuming the inside of the planet stays still.
ThermodynamicsThe attraction that is the small ones' room
Put large particles into a crowd of small ones that cannot get inside them, and the large ones begin to stick together — though nothing in the mixture attracts anything. Each large particle keeps the small ones' centres out of a thin shell around it. When two large particles touch, their shells overlap, and the overlap is handed back to the small particles as room to move in. More room is more arrangements, more arrangements is more entropy, and the large particles are pushed together by the pressure of the small ones on their outer sides. Fumio Oosawa and Sho Asakura worked it out in 1954. The force is now used to purify DNA, sort colloids onto patterned surfaces and explain why the inside of a cell behaves as though its proteins were stickier than they are.
ThermodynamicsThe bit that has to be paid for
One molecule in a box, a partition, and the knowledge of which side it went — enough, between them, to extract work from a single reservoir, which the second law forbids. The engine is real and the arithmetic is right. What closes the loophole is that the cycle does not finish until the knowledge has been thrown away, and throwing away one bit costs exactly what the expansion delivered.
ThermodynamicsThe cluster that grows where the walkers arrive
Let particles wander in one at a time from far away, each sticking where it first touches a growing clump. The rule has nothing in it about shape, and the clump that results is a lacy, branched thing whose mass grows more slowly than its area, so it gets emptier the bigger it gets. The reason is that a random walker reaches the outermost tips long before it can find its way into a gap between branches. The same arithmetic — the probability that a walker arrives is a solution of Laplace's equation — shapes electrodeposits, lightning-like discharges in plastic, fingers of water pushed into oil, and colonies of bacteria short of food.
ThermodynamicsThe diffusion that slows the longer it is watched
A random walker whose steps come at irregular times still diffuses normally, provided the waits have a finite average. Let the waits have no average — mostly short, occasionally enormous, as they are for a molecule that keeps getting stuck — and three things change at once. The spread grows more slowly than time. A diffusion coefficient measured by following one particle depends on how long it was followed. And following one particle for a long time no longer tells what many particles do: averages along a path and averages over a crowd give different laws. Tracking single molecules inside living cells runs straight into all three.
ThermodynamicsThe entropy that is still there at zero
The third law says a perfect crystal has no entropy at absolute zero. Ice has 3.41 joules per kelvin per mole left over, and the number can be recovered from one line of counting — two hydrogens near each oxygen and two far, six legal arrangements out of sixteen, R ln(3/2). The law has an escape clause and the escape clause is measurable.
ThermodynamicsThe equation that only runs forwards, and the walk underneath it
A drop of ink spreads and never gathers. The equation describing it is one of the few in physics that is not reversible — and underneath it is nothing but a coin being tossed.
ThermodynamicsThe gas that flows towards more of itself
Fick's law says a substance diffuses from where there is more of it to where there is less. In a mixture of three gases, nitrogen can do the opposite for hours — flowing into the bulb that already holds more nitrogen, and then stopping while a difference remains — and in a welded bar of steel, carbon crosses into the side that is already richer. Nothing is wrong with the second law. Diffusion flattens chemical potential, and with more than two components, or a second element changing it, that is not the same as flattening concentration.
ThermodynamicsThe heap that sets itself alight
A haystack, a coal stockpile, a bin of oily rags or a silo of damp grain can catch fire with no spark at all. A slow reaction inside makes a little heat; the heap holds it in; the warmer middle reacts faster and makes more. Whether that ends in a warm heap or a burning one is decided by a single number built from the heap's size, the air's temperature and the reaction's speed — and past one value of it there is no steady temperature at all. The critical size shrinks steeply as the weather warms, and the heap gives almost no warning before it goes.
RelativityThe heat that arrives before it could
Release a pulse of heat at one point, and the diffusion equation — the law that has described heat flow since Fourier — says the temperature rises everywhere at once, however far away. A thermometer a kilometre off registers a change the instant the heat is released. That is an infinite signal speed, and relativity forbids it. The flaw is harmless for a kettle and fatal for a relativistic fluid. The repair is a relaxation time: heat flow takes a moment to respond to a temperature gradient. With it the equation carries heat at a finite speed, sends a sharp front ahead of the spreading warmth, and turns short-wavelength heat into a damped wave.
ThermodynamicsThe hotter start that cools first
Put two identical systems, one warm and one hot, into the same cold bath, and common sense says the warm one reaches the bath's temperature first, since the hot one has further to go. The claim that hot water sometimes freezes before warm water — the Mpemba effect — has been argued over for sixty years and does not survive careful measurement. But a cleaner version of it is real and has been observed: in systems whose relaxation has a slow route and a fast one, a hotter start can miss the slow route entirely and overtake a cooler start, exponentially. Whether a system cools quickly depends not on how far it is from equilibrium but on how much of the slowest way back it needs.
ThermodynamicsThe ice that grows more slowly the thicker it gets
A lake under air ten degrees below freezing grows eleven centimetres of ice on the first day and only another eighteen in the following six. The ice forms at its underside, and every gram of it releases latent heat that must be carried up through the ice already there before more can form: the ice is its own insulation. The thickness therefore grows as the square root of time, and the rule, Stefan's, depends on temperature and time only through their product — the freezing degree-days that lake-ice forecasters count. A few centimetres of snow on top slows it more than any amount of cold speeds it up.
ThermodynamicsThe insulation that makes a wire lose more heat
Wrap a hot water pipe in glass wool and it loses less heat. Wrap a thin electrical wire in PVC and it loses more — four times more, at the best thickness — and runs cooler for it. The insulation adds a resistance to heat flowing through it, but it also adds surface for the heat to leave from, and around a thin enough cylinder the surface wins. The crossover is a radius, k/h, set by the insulation and the air; below it, more insulation means more heat lost, and a small enough ball cannot be insulated by anything wrapped round it.
ThermodynamicsThe markers that move because atoms are unequal
In 1947 Ernest Kirkendall and Alice Smigelskas wound fine molybdenum wires around a bar of brass, plated it thickly with copper, and heated it for fifty-six days. The wires, which do not dissolve in either metal, ended closer together: the brass inside them had shrunk. Zinc had diffused out of the brass faster than copper diffused in, and the lattice planes of the brass had been taken away along with the zinc. If atoms in a metal moved by swapping places with each other, the two flows would have had to be equal. They were not, and the only way the books balance is if atoms move by jumping into vacancies — empty lattice sites — that flow the other way. The wires were the first direct evidence that diffusion in metals runs on holes.
ThermodynamicsThe metal that feels colder than the wood
A steel railing and a wooden bench in the same shade are at the same temperature, and the railing feels much colder. The usual explanation, that metal conducts heat better, is half the answer, and it gets water wrong. When two bodies touch, the surface between them jumps at once to a temperature that then stays fixed, a weighted average of the two in which each body's weight is the square root of its conductivity times its heat capacity per volume. Skin at 33 °C touching steel at 20 °C meets it at 21; touching wood, at 30. The nerves report the meeting temperature, not the object's.
ThermodynamicsThe precision a clock pays for in heat
Anything that counts — a molecular motor stepping along a filament, a chemical oscillator keeping time in a bacterium, a clock ticking on a wall — has to be driven, because a count that is not driven runs backwards as often as forwards. The heat it gives off buys it regularity, and there is an exact floor under the price: the squared relative uncertainty of the count, times the entropy produced, is never less than two in units of Boltzmann's constant.
ThermodynamicsThe ring that forgets and then remembers
Put a few hundred balls on a ring, all white, and mark a handful of the gaps between them. Each tick, every ball moves one place round and changes colour if it crosses a mark. Nothing is random and everything can be run backwards. Yet the colours mix, half and half, exactly as Boltzmann's equation for a gas says they should, and the entropy rises to its maximum and stays there — until, after one full turn, every ball is white again. Mark Kac built the model in 1956 to show where the arrow of time in Boltzmann's equation comes from, and what it quietly assumes.
ThermodynamicsThe rings a reaction lays down in a gel
Let one salt soak into a tube of jelly that holds another, and where they meet a solid should form, spreading smoothly behind the advancing front. It does not. It forms in sharp, separate bands, close together near the entrance and further and further apart, each one a fixed multiple of the distance of the last. Raphael Liesegang saw the rings in 1896 and they have been found since in rocks, in agate, in gallstones and in microchips. Nothing in the jelly is patterned to begin with. The pattern comes from a solid that will not start until the solution is overloaded, and that then empties the solution around it.
ThermodynamicsThe second law, with a probability attached
Entropy increases, on average. For a small system pulled quickly, individual runs go the other way — and how often is not a matter of taste but an exact number, fixed by a relation with no adjustable constant in it and no requirement that anything be near equilibrium.
ThermodynamicsThe speed limit that does not care how big the molecules are
Two molecules in water cannot react faster than they can find each other, and how fast they find each other is set by diffusion. A bigger molecule is an easier target, so it seems a reaction between big molecules should be faster. It is not: a molecule twice as big is twice as easy to hit and wanders half as fast, and the two cancel exactly. Every reaction that happens at the first touch runs at the same rate, about seven billion per molar per second in water, whether the partners are ions or proteins — a speed limit written by the viscosity of water and the temperature, and nothing else.
ThermodynamicsThe summer that reaches the cellar in December
Drive the diffusion equation at its boundary instead of releasing something into it and the solution is a decaying, lagging oscillation with a single length in it. That length governs both the shrinking and the delay, which is why the depth at which the ground is coldest in August is fixed by the same number as the depth at which the seasons stop being felt at all.
ThermodynamicsThe transition with nothing to order
Every transition in this collection so far has an order parameter — a quantity that is zero on one side and not on the other. In two dimensions a continuous symmetry cannot break at any temperature above zero, so there is nothing for such a quantity to be, and by the usual reckoning there can be no transition. There is one anyway, and what changes at it is whether vortices are bound in pairs.
ThermodynamicsWhat a system actually minimises
A ball falls to the bottom of a bowl and a gas fills a room, and neither of those is the rule. A system in contact with a large reservoir minimises U − TS, and the minus sign is the reservoir's own entropy written in the system's variables — which is why a rubber band pulls harder when it is heated.