The ceiling on a heat engine
At its defaults it draws the ceiling on a heat engine. Maximum possible efficiency against the ratio of cold to hot reservoir temperature. Reaching 100% would need a cold reservoir at absolute zero. The line is marked at ratios of 0.9, 0.7, 0.5, 0.25, where the ceiling stands at 10%, 30%, 50%, 75%.
engine-efficiency is one function in lib/figures/thermal.js —
cycles, distributions and the statistics underneath them. Everything below came out
of it during this build, at parameters taken from the essays rather than invented for this
page. A figure here is the figure a reader meets in an essay, and if the generator changes,
this page changes with it.
At its defaults
Drawn even though every essay passes options, because a default nothing exercises is a trap for the next essay to call this with none — which has happened here twice.
Maximum possible efficiency against the ratio of cold to hot reservoir temperature. Reaching 100% would need a cold reservoir at absolute zero. The line is marked at ratios of 0.9, 0.7, 0.5, 0.25, where the ceiling stands at 10%, 30%, 50%, 75%.
A fridge with no work going into it, and its ceiling
The options are the ones A fridge with no work going into it passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
How much heat a three-reservoir machine can lift out of a cold space per unit of heat supplied to drive it, against the temperature of the driving heat, for 3 cold temperatures and an ambient of 300 kelvin. No work enters or leaves: the machine takes heat in at the top, takes heat in at the bottom, and rejects the sum at ambient. That it can do anything at all is the surprise — the second law allows heat to be moved up a gradient provided a larger flow is moved down one, and the accounting is a single inequality in the three entropy flows. The ceiling is the product of two familiar expressions, and at 450 kelvin driving a 253-kelvin space it is 1.79. The marks are what real machines achieve, which is a fifth to a third of it — absorption refrigeration is not efficient and is chosen when the heat is free and the silence and the absence of moving parts are worth something.
Three flows of heat and no work anywhere
The options are the ones A fridge with no work going into it passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The heat crossing each boundary of a reversible three-reservoir refrigerator, per joule supplied to drive it, with the entropy each flow carries printed beside it. Heat enters at 450 kelvin and at 253, and the sum of the two leaves at 300. No work crosses any boundary in either direction, so the first law is simply that the heats add. The second law is the interesting one: the entropy arriving is 0.00931 joules per kelvin and the entropy leaving is 0.00931, and they are equal — which is exactly the condition that fixes how much heat could be lifted. A joule arriving at a high temperature carries little entropy and a joule arriving at a low one carries a lot, so the driving heat's entropy budget is what pays for the cold heat's.
Three flows of heat and no work anywhere
The options are the ones A fridge with no work going into it passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
The heat crossing each boundary of a reversible three-reservoir refrigerator, per joule supplied to drive it, with the entropy each flow carries printed beside it. Heat enters at 380 kelvin and at 283, and the sum of the two leaves at 305. No work crosses any boundary in either direction, so the first law is simply that the heats add. The second law is the interesting one: the entropy arriving is 0.01160 joules per kelvin and the entropy leaving is 0.01160, and they are equal — which is exactly the condition that fixes how much heat could be lifted. A joule arriving at a high temperature carries little entropy and a joule arriving at a low one carries a lot, so the driving heat's entropy budget is what pays for the cold heat's.
A fridge with no work going into it, and its ceiling
The options are the ones A fridge with no work going into it passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
How much heat a three-reservoir machine can lift out of a cold space per unit of heat supplied to drive it, against the temperature of the driving heat, for 3 cold temperatures and an ambient of 300 kelvin. No work enters or leaves: the machine takes heat in at the top, takes heat in at the bottom, and rejects the sum at ambient. That it can do anything at all is the surprise — the second law allows heat to be moved up a gradient provided a larger flow is moved down one, and the accounting is a single inequality in the three entropy flows. The ceiling is the product of two familiar expressions, and at 450 kelvin driving a 240-kelvin space it is 1.33. The marks are what real machines achieve, which is a fifth to a third of it — absorption refrigeration is not efficient and is chosen when the heat is free and the silence and the absence of moving parts are worth something.
The region a heat-driven fridge can work in
The options are the ones A fridge with no work going into it passes. A branch drawn at its own defaults instead would be a picture no essay asked for and no assertion has been run against.
Contours of how much heat a reversible three-reservoir machine lifts per joule supplied, in the plane of the driving temperature and the temperature of the cold space, at an ambient of 300 kelvin. Two edges bound the region and neither is negotiable: the driving heat must be above ambient, or there is no engine, and the cold space must be below it, or there is nothing to refrigerate. Approaching either edge sends the performance to zero. The contours run steeply, which is the practical content: deep refrigeration from modest heat is nearly impossible, and mild cooling from hot heat is easy. That is why absorption machines are used for air conditioning, where the cold space is fifteen degrees below ambient, and almost never for freezing.
What checks it
physicscheck asserts something about engine-efficiency that
could fail — it draws it and measures the result against a value reached some other
way.
Across the library: 100 interrogated, 2 exercised only, 1 untouched, of 103. Read out of the gate's source by the gate's own two patterns — and the gate's last claim fails the build if that read disagrees with what it was handed while running.
Where it is called
Changing this generator changes every figure on this list. That is what makes the list worth publishing rather than keeping in a check script.
A fridge with no work going into it
Every engine here so far turns heat into work or work into a heat flow. A machine exchanging heat with three reservoirs and doing no work at all can still move heat from cold to hot, and the ceiling on how much is the product of two Carnot expressions — an engine's efficiency times a fridge's coefficient of performance. A gas flame makes ice, and the accounting is one inequality in three entropy flows.
ThermodynamicsAn engine with one number in it
A thermoelectric couple has no moving part and no working fluid, and its efficiency is the Carnot value multiplied by a factor containing exactly one dimensionless group of material properties. Sixty years of effort have moved that group from about one to about two, and the reason it is hard is that its three ingredients are not independent: raising the conductivity ruins the coefficient it is squared against, and the only lever that is really free is the heat the lattice carries.
ThermodynamicsEntropy is a count, and the arrow of time is arithmetic
Nothing in mechanics prefers a direction. Entropy is not a force pushing things toward disorder — it is the observation that some outcomes have vastly more ways of happening than others.
ThermodynamicsThe ceiling on every engine, set before it was designed
There is a maximum efficiency no heat engine can exceed, and it depends on nothing but two temperatures. Not the fuel, not the working substance, not the cleverness of the engineer.
ThermodynamicsThe engine a fluctuation cannot run
A ratchet lets a shaft turn one way and not the other. Put a paddle in a gas on the same shaft and molecular collisions appear to become a lifted weight — an engine running on one reservoir. It does not work, and following exactly why turns the second law from a prohibition into a mechanism: the pawl is as warm as the gas, and it lifts whenever it is asked to.
ThermodynamicsThe engine that has to finish
Carnot's ceiling is exact and it is reached only by an engine that takes for ever, because a reversible heat flow needs a vanishing temperature difference to drive it. Ask instead for the most power rather than the most work per joule of heat, and the answer is a different function of the same two temperatures — and three measured power stations sit on it rather than on the ceiling.
ThermodynamicsThe engine that pays back more than it takes
Carnot's argument puts a ceiling on how much work a flow of heat can be made to do. Run the same cycle backwards and the ceiling inverts into a floor that is greater than one — so a machine can deliver three or four joules of heat for every joule it consumes, and a perfectly efficient electric heater is the worst way to warm a room.
ThermodynamicsThe temperature an engine really takes its heat at
Carnot's ceiling is set by two temperatures, and no engine that burns fuel takes its heat in at one temperature or gives it out at another. It takes heat over a range, from the moment combustion starts to the moment it ends. For any reversible cycle there is an exact replacement for Carnot's two numbers: the average temperature at which heat arrives and the average at which it leaves, each weighted by the entropy the heat carries. The gap between a real cycle and Carnot is a gap between those averages and the extremes.
ThermodynamicsThe work left in two buckets of water
Carnot's ceiling assumes reservoirs so large that taking heat from one and giving it to the other changes neither temperature. Two buckets of water are not reservoirs. Run the best possible engine between a hot one and a cold one and both temperatures move, the efficiency available shrinks as they do, and the engine stops when they meet — at the geometric mean of the starting temperatures, not the ordinary one. The work it delivered is exactly the difference between those two meeting points, and it is far less than the starting temperatures promise.