The collection

Every essay — page 31

One idea per essay, ordered so that the earlier ones set up the later ones — but nothing here depends on being read in sequence.

Mechanics

Motion, force, and the quantities that refuse to change.

Waves

Oscillation, and everything that turns out to be an oscillation.

Optics

Light, and the small number of rules it obeys.

Electromagnetism

Charge, field, and the lines drawn between them.

Thermodynamics

Heat, disorder, and the one law with a direction in it.

Latent heat of boiling against boiling point. The heat needed to boil one mole of a liquid at its normal boiling point, against that boiling point, both on logarithmic axes, for twenty-one substances from helium to sodium. The line is ΔH = 87.2 J/(mol K) × Tb, the mean entropy of boiling of the ordinary liquids boiling between 250 and 700 K, which scatter about it by 3.3 per cent; the ordinary liquids as a whole (blue), from neon at 27 K to sodium at 1,156 K, by 10.0 per cent, the coldest lying low. Water, ammonia and the alcohols (red) need more heat than the line predicts, acetic acid (green) less; the quantum liquids helium and hydrogen (violet) fall far below.

The entropy every liquid gains on boiling

Divide the heat it takes to boil a liquid by the temperature at which it boils, and for benzene, chloroform, acetone, hexane, ether and carbon tetrachloride the answer comes out within a few per cent of the same number — about ten and a half times the gas constant. Frederick Trouton noticed it in 1884. It is a statement about entropy, and once it is read that way the liquids it fails for become the interesting ones: water and the alcohols, whose hydrogen bonds hold the liquid in order; acetic acid, whose vapour is made of pairs; and helium, whose liquid is already as disordered as quantum mechanics allows.

5 figures · part 12 on Phase change
A cluster grown by random walkers. 3000 particles, each released far away to wander at random on a square grid until it first touches the cluster and sticks there, starting from one seed at the centre. Colour marks the order of arrival: the first third (violet), the second (blue), the last (red). The cluster is 220 grid steps across, branched and open, and almost every late arrival is at the outer tips: walkers wander into the outer branches long before they can find their way into the gaps between them. The gaps never fill.

The cluster that grows where the walkers arrive

Let particles wander in one at a time from far away, each sticking where it first touches a growing clump. The rule has nothing in it about shape, and the clump that results is a lacy, branched thing whose mass grows more slowly than its area, so it gets emptier the bigger it gets. The reason is that a random walker reaches the outermost tips long before it can find its way into a gap between branches. The same arithmetic — the probability that a walker arrives is a solution of Laplace's equation — shapes electrodeposits, lightning-like discharges in plastic, fingers of water pushed into oil, and colonies of bacteria short of food.

5 figures · part 11 on Diffusion
A heat capacity that goes up and comes down. The heat capacity per system, in units of Boltzmann's constant, against temperature in units of the level spacing over k: for a system with two levels (red), Schottky's hump x²eˣ/(1 + eˣ)², x = Δ/kT, and for a harmonic oscillator with the same spacing (blue), which climbs to one k and stays there. Both are frozen out when kT is well below the gap. The oscillator then fills its unending stack of levels and reaches equipartition's value. The two-level system peaks at 0.439k when kT = 0.417Δ, and then, with both levels nearly equally occupied and nothing higher to go to, it stops absorbing heat: its capacity falls back towards zero as 1/T².

The heat capacity that goes up and comes down

Equipartition promises every way a system can move a fixed share of heat, and for a harmonic oscillator the promise is kept: once the temperature is high enough, it holds one k per oscillator and goes on holding it. A system with only two levels cannot keep it. It absorbs heat while its upper level is filling, then stops — the two levels equally full and nowhere higher to go — so its heat capacity rises to a peak and falls back to zero. The hump, named after Walter Schottky, is the signature of a degree of freedom with a ceiling, and the area under it counts how many states were there.

5 figures · part 9 on Equipartition
Where skin and the thing it touches meet. Temperature across the contact between skin at 33 °C (left) and a block at 20 °C (right), against distance from the contact in millimetres, at 0.1, 1 and 10 s after touching, for steel (blue) and pine wood (red). Each pair of curves is two error functions meeting at the contact, and the meeting temperature does not change with time: 21.0 °C against steel and 30.3 °C against wood. The nerve endings a fraction of a millimetre under the skin report something close to that interface temperature, so the steel feels like an object at 21 °C and the wood like one at 30 — although both are at 20. The profiles spread as the square root of time, much further into the steel than into the wood.

The metal that feels colder than the wood

A steel railing and a wooden bench in the same shade are at the same temperature, and the railing feels much colder. The usual explanation, that metal conducts heat better, is half the answer, and it gets water wrong. When two bodies touch, the surface between them jumps at once to a temperature that then stays fixed, a weighted average of the two in which each body's weight is the square root of its conductivity times its heat capacity per volume. Skin at 33 °C touching steel at 20 °C meets it at 21; touching wood, at 30. The nerves report the meeting temperature, not the object's.

5 figures · part 12 on Diffusion

Relativity

Space and time, drawn on the same axes.

In the rod's frame: a long rod threads through, front first. The same events seen from the rod's own frame, computed by transforming each point's motion from the hole's frame. Here the rod is its full length and the hole is the contracted one, 0.60 of it, sweeping left at 0.8c — a long rod over a short hole. But the moment each point starts to fall is not one moment in this frame: the front end starts at t′ = −1.07, the rear end at −0.27, and each point then falls at γu = 0.50c. While the start of the fall runs back along it the rod is bent, level behind and sloping in front; once every point is falling it is straight again and tilted, front down, by 21.8°. It threads through the hole front first as the hole slides under it, each part dropping below the plate just before the plate's far edge reaches it. It passes through in both frames; only the order of events along it differs.

The rod that is level for only one observer

A metre rod slides at high speed over a metre-wide hole in a thin plate. In the plate's frame the rod is contracted and drops through. In the rod's frame the hole is contracted, the rod is far too long for it, and it drops through anyway — because the instruction 'every point starts to fall now' names a different now for the rod. Its front end starts first, the start runs back along it, and the rod tips into the hole like a spear. Whether a moving thing is level is a question about which events are simultaneous, and so it has an answer only for an observer.

5 figures · part 6 on Simultaneity
Light inside an accelerating rocket travels on circles. Rays of light leaving one point inside a rocket with constant acceleration, drawn in the rocket's own coordinates: height above the horizon up the page, in units of c²/a (one light-year for one gravity), and distance across. Each ray is a straight line in an inertial frame, transformed event by event. Launched across the rocket (0°) or at +30°, +60°, −30°, −60°, every ray is an exact semicircle centred on the horizon, with radius 1.000, 1.155, 2.000, 1.155, 2.000: the rays bend down towards the horizon and meet it at right angles. A ray sent straight up stays straight. These are the straight lines of the hyperbolic plane, although the spacetime inside the rocket is flat.

The rocket in which light travels on circles

Inside a rocket that accelerates for ever at a constant rate, a beam of light sent across the cabin sags towards the floor, as Einstein argued it must if acceleration and gravity are indistinguishable. Followed further than any cabin, the sag turns out to be exact geometry: every ray inside the rocket is a perfect semicircle centred on the horizon below, and the rays obey the rules of a non-Euclidean plane in which the angles of a triangle add to less than two right angles. The spacetime in the rocket is flat; the curvature belongs to the clocks.

5 figures · part 6 on Accelerated frames
Where the spot is, and when, for three sweep speeds. A spacetime diagram of the spot a turning beam makes on a flat screen at distance D: position along the screen across, the time at which light arrives there up, both in units of D and D/c, for beams sweeping the screen's nearest point at ωD = 0.5c, 1.0c, 3.0c. Each curve is the arrival time t(x) = atan(x/D)/ω + √(D² + x²)/c. Every curve has a lowest point on the approaching side — at x = −1.25, −0.79, −0.32 D respectively — because far out the beam strikes the screen obliquely and its sweep along the screen outruns light whatever ω is. Light reaches that point first: the spot is born there, as a pair, one running back up the screen and one forward. The faster the sweep, the nearer the centre the birth. The faint dashed lines are light signals, slope one. Wherever a spot's track is flatter than they are, it is a sequence of events no signal could connect.

The spot that outruns light and carries nothing

Flick a laser pointer across the face of the Moon and the spot it makes crosses the Moon faster than light. Nothing is wrong with relativity: the spot is not a thing, and no part of it travels from one side to the other. Each lit point is lit by its own light, sent from the hand. What makes the spot worth studying is how strange such a non-thing is allowed to be. It can be born in the middle of the screen as a pair running apart; its speed can be made infinite, or reversed, merely by watching it from a moving frame; and the composition of velocities that caps everything real has nothing to say about it.

5 figures · part 8 on Velocity-addition
How fast each point of a fast wheel moves. The speed through the ground of each point on the rim of a rolling wheel, in units of the speed of light, against the point's angle round the rim measured from the bottom, for axles moving at 0.5c, 0.8c, 0.95c. The dashed curves are the everyday answer, 2v sin(α/2), which puts the top at twice the axle's speed and would carry it past light. Composed relativistically, the bottom is still at rest and the top moves at 2v/(1 + v²/c²): 0.800c, 0.976c, 0.999c, always below c. Every point of the rim stays slower than light, and the fast part of the wheel is flattened into a broad plateau over the top.

The wheel whose top cannot go twice as fast

The top of a rolling wheel moves at twice the speed of its axle, and the bottom is momentarily at rest — two facts every cyclist's spokes show, blurred at the top and sharp at the bottom. Roll the wheel at a large fraction of the speed of light and the second fact survives exactly while the first cannot: the top moves at 2v/(1 + v²/c²), never as fast as light. Caught at one instant of the ground's time the spokes are bent, and over one turn the wheel advances not the circumference measured from its axle but γ times it — the rim's own length, laid down on the ground by a contact point that does not move.

5 figures · part 9 on Velocity-addition

Quantum

Where the continuous picture runs out, and what replaces it.

Four operations on one half, four states of the pair. The sender holds one half of an entangled pair prepared in the state |Φ+⟩ = (|00⟩ + |11⟩)/√2, the receiver the other. To send two bits she applies one of four operations to her half alone — do nothing, flip it (X), shift its phase (Z), or both — and sends it. The table gives, computed from the state vectors, the probability that the receiver's joint measurement of both halves in the Bell basis returns each of the four Bell states: one on the diagonal, zero everywhere else. Four perfectly distinguishable outcomes from one transmitted qubit is two bits. Sent without the pair, a qubit can carry at most one.

The qubit that carries two bits

A single quantum two-state system, sent from one person to another, can carry at most one bit of message — a theorem, not an engineering limit. If the two already share half each of an entangled pair, the sender can do one of four things to her half alone, send just that half, and the receiver can tell which of the four she did. Two bits arrive on one qubit. Nothing is free: the shared pair had to be delivered, and counted honestly the rate is still a bit per qubit. What entanglement buys is the freedom to send half the message before the message exists, and it also buys privacy, since the qubit in transit carries nothing at all on its own.

5 figures · part 6 on Entanglement
Ramsey fringes: two short pulses and a long wait. The fraction of atoms found in the upper state against the detuning of the drive from the atoms' frequency, in cycles per pulse length, for two π/2 pulses of length τ separated by a free time T = 10τ (solid), computed from the exact two-level evolution. Fringes of period 1/T ride under an envelope set by the short pulses (dotted, the response to one pulse of length 2τ). The central fringe is 0.0444 cycles per τ wide at half height, close to 1/2T. A single long pulse covering the same total time, 12τ (dashed), gives a peak 0.0666 wide: 1.50 times wider, and with no way of telling a large detuning from a small one by its side fringes alone.

The wait that sets the precision

To measure an atom's frequency, the obvious method is to drive it and look for the response, and the sharpness of the answer is set by how long the drive lasts. Norman Ramsey found in 1949 that most of the drive is wasted. Two short pulses with a long wait between them do better than one long pulse, because during the wait the atom keeps its own time undisturbed, and any difference from the drive's time piles up as an angle the second pulse can read. Every primary clock in the world runs on that idea, and its precision is set by two numbers: how long the atoms can be left alone, and how many of them there are.

5 figures · part 6 on Measurement
Absorption below and above the gap. The light absorbed by a direct-gap crystal against photon energy measured from the gap, in units of the exciton's Rydberg, from Elliott's formula with each line broadened to a half-width of 0.06 Rydberg (solid), beside the absorption the same crystal would have if electron and hole did not attract (dashed), which rises from zero as the square root of the energy above the gap. Below the gap the attraction adds a series of lines at −1, −1/4, −1/9 … Rydberg, the hydrogen series scaled down, with strengths falling as 1/n³, crowding towards the gap. Above it the continuum is lifted: the attraction pulls each free pair together, and at the gap itself the absorption is a finite step rather than zero.

The hydrogen atom inside a crystal

Light absorbed by a semiconductor lifts an electron across the gap and leaves a hole behind, and the two attract. In an ordinary crystal they bind into a copy of the hydrogen atom, with the same series of levels and the same 1/n² — but the crystal screens their attraction and lends them light masses, so the copy is a few thousand times shallower and several hundred times larger. That rescaling is the whole theory, it predicts lines below the gap and a finite step at it where no attraction would give a smooth rise from zero, and it says which crystals keep their excitons at room temperature.

5 figures · part 6 on Bands
Two lifetimes a thousand times apart. The fraction of positronium atoms surviving in the ground state against time since formation, on a logarithmic time axis, for the spin singlet, para-positronium (red), and the spin triplet, ortho-positronium (blue), in vacuum. Para lives 125.1 ps and ortho 142.1 ns, a ratio of 1135. The lowest-order formulas give 124.5 ps, from α⁵mc²/2ħ, and 138.7 ns, from 2(π² − 9)/9π · α⁶mc²/ħ; the ratio is almost entirely one extra power of the fine-structure constant, the price of a third photon.

The atom with no nucleus

An electron and a positron can bind into an atom whose structure is hydrogen's with every level halved and every size doubled, because neither partner sits still at the centre. The atom then destroys itself, and how fast depends on one symmetry. With the two spins opposed it vanishes in 125 picoseconds as two photons; with them aligned it must make three, and lives 142 nanoseconds — over a thousand times longer — for no reason but that a rule about charge conjugation forbids the shorter route.

5 figures · part 6 on Atomic structure

Fluids

Matter that will not hold a shape, and the forces that act in it anyway.

Astrophysics

Gravity read as geometry, and the laws carried where no laboratory can follow.

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