Illustrated Physics
physics, drawn
The collection

Every essay — page 25

One idea per essay, ordered so that the earlier ones set up the later ones — but nothing here depends on being read in sequence.

Mechanics

Motion, force, and the quantities that refuse to change.

Restitution with nothing lossy in it. The coefficient of restitution of a perfectly elastic ball striking a large, perfectly elastic plate, against Zener's parameter λ, which grows as the square of the ball's radius over the plate's thickness and weakly with speed. At λ = 0 the ball comes back at its arrival speed. The rebound falls below half at λ ≈ 0.65, with no friction, plasticity or damping anywhere — the missing energy is travelling outward through the plate as bending waves. Marked: a steel ball 20 mm across at 1 m/s on steel plates 5 mm thick (λ = 0.94), 10 mm thick (λ = 0.23), 20 mm thick (λ = 0.06).

The bounce an elastic plate cannot give back

Drop a steel ball on a thick steel block and it bounces almost to where it started. Drop it on a steel plate five millimetres thick and it comes back at barely half its speed, although steel on steel is about as elastic as materials get and nothing in the impact is plastic, sticky or damped. The energy has not been turned into heat. It has been turned into waves, running out through the plate faster than the ball can take them back — and a ball striking a longer rod loses energy the same way, by leaving it ringing.

5 figures · part 7 on Momentum The wobble slows as the body yields. The period of the Earth's free wobble against how far the body yields to its own rotation, measured as the Love number k over its value for a fluid Earth, kₛ = 0.941, computed from the Earth's flattening. A rigid Earth, at zero, wobbles in 303.6 days, Euler's period. The observed 433 days requires k/kₛ = 0.299, an effective k of 0.281: the Earth yields about 30 per cent as much as a fluid would. The period grows without limit as the body approaches a fluid, because a fluid body's bulge re-forms round any new spin axis and leaves nothing to push the axis back.

The wobble that is slow because the Earth gives

Euler worked out in 1765 that a spinning, flattened Earth whose axis is knocked slightly off its figure should wobble, the pole wandering in a small circle once every ten months. Astronomers looked for a ten-month period for a century and found nothing. In 1891 Seth Chandler found a wobble of fourteen months instead. The four extra months are not an error in Euler's arithmetic. They are the Earth yielding: its bulge partly re-forms round the displaced axis, weakening the torque that drives the wobble, and the lengthening measures how soft the planet is.

5 figures · part 8 on Rotation The shear a pushed contact carries, and where it gives. Across a Hertzian contact of radius a, the normal pressure as a fraction of its peak, which is also the friction limit μp in units of μp₀ (dashed), and the shear traction for a sideways push of 0.3, 0.6, 0.9 times the load that would slide it, μP. Where the shear reaches the dashed ceiling the surfaces slip; inside, they stick. At 0.3 μP the stuck disc has a radius of 0.89a, so 21 per cent of the contact area is slipping; at 0.6 μP the stuck disc has a radius of 0.74a, so 46 per cent of the contact area is slipping; at 0.9 μP the stuck disc has a radius of 0.46a, so 78 per cent of the contact area is slipping. The shear is highest just inside the slipping ring and, in an elastic contact that simply stuck everywhere, would be infinite at the rim: slip at the edge is what removes that singularity.

The contact that slips before it slides

Static friction is supposed to hold perfectly until the load reaches μ times the normal force and then give way. Two elastic bodies pressed together do something else. Push a ball sideways on a flat with any force at all and a ring at the edge of their contact is already slipping, while the centre stays stuck. As the push grows the ring spreads inward, and gross sliding is only the moment the stuck centre shrinks to nothing. Shake the push back and forth and the ring slips each way on every cycle. The contact then loses energy though it never slides, as the cube of how hard it is shaken.

5 figures · part 6 on Friction A bound state that lives outside its well. The radial probability density of the one bound state of a square well of radius R, against distance in units of R, for four depths just past the one that first binds a state. In units of ε = ħ²/2μR², a state bound by 0.00589 ε has 93 per cent of its probability outside the well and a mean radius of 7.0 R; a state bound by 0.0397 ε has 82 per cent of its probability outside the well and a mean radius of 3.0 R; a state bound by 0.245 ε has 62 per cent of its probability outside the well and a mean radius of 1.5 R; a state bound by 1.4 ε has 35 per cent of its probability outside the well and a mean radius of 0.9 R. The more weakly the state is bound, the further its exponential tail reaches, and the less of it is where the force is.

The molecule that lives outside its own well

The harmonic picture describes the bottom of a well, where a molecule vibrates near the length of its bond. The last bound level lives at the top, and when it is bound by almost nothing it is not near the bond at all. Two helium atoms whose potential well bottoms out at three ångströms form a molecule whose atoms sit on average about fifty ångströms apart, most of the time where the force between them is negligible. Such a state forgets the shape of the well that made it. Its size, its binding and the way it scatters are all set by one number, and nothing inside the well can be read from them.

5 figures · part 6 on Harmonic approximation

Waves

Oscillation, and everything that turns out to be an oscillation.

Echoes from a layer that thins to nothing. Synthetic seismic echoes from a layer between two identical rocks — the top reflecting +R, the base −R — for thicknesses of 0, 5, 10, 15, 20, 25, 30, 40, 50, 60, 75, 100 m, sounded with a 30 Hz pulse in rock of 3000 m/s, whose wavelength in the layer is 100 m. Time runs downward; each trace is one thickness. Thick, the layer gives two separate echoes, one from each face, and its thickness can be read from the time between them. As it thins the two echoes overlap and merge. Near 20 m, about a fifth of a wavelength, they interfere constructively and the combined echo is strongest, 1.45 times one face's echo. Thinner still, the combined echo keeps a fixed shape — the pulse's derivative — and simply weakens in proportion to the thickness; nothing in its timing changes.

The layer too thin to see

A seismic survey sends a pulse of sound into the ground and listens to the echoes from every boundary where the rock changes. A thick layer returns two echoes, one from its top and one from its base, and the time between them gives its thickness. A thin one returns one echo, and below about a quarter of a wavelength the timing says nothing more: every thin layer looks the same, just weaker as it thins. It has not become invisible. It has become unmeasurable in the one way that was being used, and its thickness has moved into the echo's strength and its spectrum.

5 figures · part 6 on Impedance A tiny ripple that grows, peaks, and gives the energy back. The highest point of a wave train's envelope against time, starting from an even train of amplitude 1 with a ripple of 1 per cent at the fastest-growing wavenumber, integrated from the nonlinear Schrödinger equation. For a while nothing happens that the eye could see; the ripple grows exponentially from a per cent. Then, near t = 5.6, the energy of a whole modulation period gathers into one crest 2.41 times the original amplitude — 1 + √2, the height of the Akhmediev breather this wavenumber produces. Then it spreads out again, and by t ≈ 11 the train is almost even once more, its highest point 1.01: the energy returns to where it came from, and the cycle repeats, the crest rising again near t = 17. The wave's total norm is conserved throughout to a part in a hundred million.

The even wave train that cannot stay even

In the mid-1960s a team at the National Physical Laboratory tried to make a long, perfectly regular train of waves in a towing tank, and could not: however carefully they set the paddle going, a few hundred metres down the tank the waves had bunched into groups. Their paddle was not at fault. A uniform train of steep waves on deep water is unstable — small modulations of its height grow, the energy of many waves gathers into a few, and then, astonishingly, gives itself back. Out of that instability comes a wave three times the height of the sea around it, with no history before and none after.

5 figures · part 7 on Wave packets A clock that takes the drive's frequency over a whole range. The frequency a self-sustained oscillator actually runs at, relative to the frequency of a weak drive, against how far its own natural frequency is from the drive's, both in units of the locking strength K. Without the drive it would lie on the dashed diagonal, keeping its own frequency. With it, every natural frequency within ±K of the drive's is pulled all the way in: the oscillator runs at exactly the drive's frequency, a flat plateau where it has abandoned its own. Outside the plateau it runs free again but not at its own frequency; it is pulled towards the drive, its offset shrinking from the detuning to the square root of (detuning squared minus K squared) — 0.66 K instead of 1.2 K just outside, 2.83 K instead of 3 K further out.

The clock that is pulled into step

In 1665, ill in bed, Christiaan Huygens noticed that two of his pendulum clocks hanging from the same beam were swinging in exact opposition, and that however he disturbed them they returned to it within half an hour. A clock is not a passive resonator waiting to be pushed; it keeps its own time, by its own mechanism. What a weak push can do to it is not change how strongly it swings but pull its phase — and within a range of frequencies set by the push's strength, pull it all the way into step. The same arithmetic locks lasers, pacemaker cells, power stations and the body's daily clock.

5 figures · part 7 on Resonance

Optics

Light, and the small number of rules it obeys.

Too small blurs by diffraction, too large by shadow. The size of the image of a distant point through a pinhole 100 mm from the screen, in 550 nm light, against the hole's diameter, both on logarithmic axes. The dashed lines are the two simple estimates: the hole's own shadow, as wide as the hole, and the diffraction spread, 2.44λf/d. The dots are the diameter holding half the light, computed from the Fresnel diffraction integral. They follow the shadow for large holes and the diffraction for small ones, and are least — 0.207 mm — for a hole 0.336 mm across, where the simple sum of the two estimates puts its minimum at 0.366 mm. At the best hole the Fresnel number d²/4λf is 0.51: the sharpest hole, judged by where half the light lands, lets through about half of the first Fresnel zone.

The hole that makes the sharpest picture

A pinhole camera makes a picture without bending any light: a small hole lets through, from each point of the scene, only the rays that reach one small patch of the screen. A smaller hole makes a sharper picture — until it does not. Below a certain size the hole spreads light by diffraction faster than it narrows the shadow, and the picture blurs again. The best hole balances the two, and at that balance it turns out to pass about half of the first Fresnel zone of the incoming wave: the sharpest pinhole is already beginning to behave like a lens.

5 figures · part 8 on Imaging Grains that hide their own shadows. The share of the grain surface an observer can see that is also lit, against the angle between the observer's line of sight and the light's direction, for random layers of grains filling 10, 30, 50 per cent of the space, with the light 20° from the vertical. Computed by following sight lines to the first grain they meet and asking whether that point can see the source. At zero phase angle the share is exactly one: every surface the observer sees is lit, because the observer is looking along the light's own path. Away from it shadows come into view, and the share falls to 0.51, 0.63, 0.70 at 40°. The fall is fastest in the loosest layer — half of it is complete by 4.9° — and slowest in the densest, 14.2°, because long shadows between widely spaced grains need only a small change of viewpoint to be seen.

The full moon that is too bright

Half a moon shows half the lit disc, so it ought to be about half as bright as a full one — a little less, allowing for the angle. It is a tenth as bright. In the last few days before full the Moon brightens far faster than its growing area can explain, and the extra light is not reflected any more strongly. It comes from shadows disappearing. The lunar soil is a loose heap of grains, and when the Sun is directly behind the observer every grain hides its own shadow.

5 figures · part 7 on Scattering Colours that leave a grating on different roads. A pair of parallel diffraction gratings with 1,200 lines per millimetre and light arriving at 30°, drawn to scale for three wavelengths, 760, 800 and 840 nm. The first grating sends each colour off at its own angle — 24.3° for 760 nm, 27.4° for 800 nm, 30.5° for 840 nm — and the second turns them all back parallel to the input, side by side. Between the gratings the red travels the longest road: for gratings 10 mm apart the slant paths are 10.97 mm, 11.26 mm, 11.61 mm. Measured to a common wavefront after the second grating, the longer road still wins, so red arrives last: the geometry has given the pulse the opposite ordering to the one glass gives it.

The dispersion made of angles

Glass delays blue light more than red, so a short pulse that passes through glass comes out stretched with its red end first. At the wavelengths where most short-pulse lasers work, no transparent glass does the opposite. Two diffraction gratings do it with no material at all. The first spreads the colours in angle, the second turns them back parallel, and in between the red has travelled the longer road. A spread in angle, however it is made, always adds this kind of dispersion, of the sign glass cannot give. It is how every high-power ultrafast laser squeezes its pulse back after amplifying it.

5 figures · part 6 on Dispersion

Electromagnetism

Charge, field, and the lines drawn between them.

The drag peaks and then gives way to lift. The two forces on a magnet moving parallel to a thin conducting sheet, as fractions of the repulsion a perfect mirror image would exert, against the magnet's speed divided by the sheet's characteristic speed w = 2/μ₀σd, on a logarithmic axis. Drag grows in proportion to the speed at first, peaks at 1.27 w with 0.300 of the full repulsion, and then falls as w/v. Lift starts as the square of the speed, equals drag at v = w, where both are 0.293, and approaches the full repulsion at high speed: 0.900 at 10 w. The same eddy currents cause both. What changes with speed is how much of the image they form has time to sink away before the magnet has passed.

The drag that falls as the magnet speeds up

Drop a magnet down a copper pipe and it creeps, because the currents it stirs up in the metal pull back on it in proportion to its speed. Push it faster and the proportion fails: the drag rises to a peak and then falls away, while a second force, pointing straight up, grows to replace it. A magnet moving fast enough over a sheet of aluminium is not braked but held up, with lift thirty times its drag at the speed of a fast train, and the reason is that at high speed the metal has no time to forget the magnet has passed.

5 figures · part 6 on Induction

Thermodynamics

Heat, disorder, and the one law with a direction in it.

The same rate for every size of molecule. The diffusion-limited rate constant for two equal spherical molecules meeting in water at 25 °C, against their radius from 0.1 to 100 nm: 8kT/3η = 7.43·10⁹ per molar per second, flat. The dashed line is what a larger target would give if its partner kept the mobility of a 0.3 nm molecule — 7.4·10¹¹ at 30 nm — the intuition that a bigger molecule is easier to hit. Stokes and Einstein's law takes it away again: a molecule twice as big is twice as easy to hit and diffuses half as fast, and the two cancel exactly. Every reaction whose partners react at the first touch runs at close to this one number, whether the partners are ions, small organic molecules or proteins.

The speed limit that does not care how big the molecules are

Two molecules in water cannot react faster than they can find each other, and how fast they find each other is set by diffusion. A bigger molecule is an easier target, so it seems a reaction between big molecules should be faster. It is not: a molecule twice as big is twice as easy to hit and wanders half as fast, and the two cancel exactly. Every reaction that happens at the first touch runs at the same rate, about seven billion per molar per second in water, whether the partners are ions or proteins — a speed limit written by the viscosity of water and the temperature, and nothing else.

5 figures · part 8 on Diffusion The same thermal motion, spread three ways. How the thermal jiggling of a spring-mounted mass is distributed over frequency, for quality factors 3, 30, 300, with frequency in units of the resonance and the spectrum in units that make the area under each curve its mean-square displacement. All three curves enclose exactly the same area, kT/k — 1.000, 1.000, 1.000 of it in the units drawn — because equipartition fixes the energy in the spring and not how fast it changes. What the damping chooses is where that motion goes: a high Q concentrates it in a peak 100 times taller than the low-Q one, and leaves the rest of the spectrum 100 times quieter at 10 times the resonance frequency.

The noise a high Q moves out of the way

Anything held by a spring at a temperature jiggles, and equipartition says exactly how much: the mean square of its displacement is kT divided by the spring's stiffness, whatever the spring is made of and however it is damped. That looks like a floor no measurement can go below. It is a floor on the total, and the total can be moved. An oscillator with little damping puts almost all of its thermal motion into a narrow peak at its own frequency and leaves every other frequency quiet — which is why the mirrors of gravitational-wave detectors hang from fibres of glass that ring for minutes.

5 figures · part 8 on Equipartition Hydrogen ionised by heat at one end and by crowding at the other. The ionised fraction of hydrogen against the density of nuclei, at 5,000 K, 10,000 K, 20,000 K, from Saha's equation with the binding energy lowered by the neighbouring charges (solid) and without the lowering (dashed). Thin gas is ionised by the room a free electron gains; compression takes the room away and the gas recombines, as the dashed curves continue to do for ever. The solid curves turn round: at 5,000 K the gas is least ionised, 2.5·10⁻⁴ per cent, near 10²⁶ per cubic metre; at 10,000 K the gas is least ionised, 0.41 per cent, near 10²⁷ per cubic metre; at 20,000 K the gas is least ionised, 12 per cent, near 10²⁸ per cubic metre, and by 6·10²⁸ per cubic metre — 0.10 g/cm³ — every curve is fully ionised, because the ground state no longer exists. That density does not depend on the temperature at all.

The pressure that ionises

Squeeze a hot gas of hydrogen and Saha's equation says it recombines: a free electron has less room to be in, and room was what paid for its freedom. Squeeze it far enough and it comes apart again, completely, at any temperature — not because the room has grown but because the atom has nowhere left to be. Crowded to within a few atomic radii of each other, hydrogen atoms have no bound state, and their electrons, freed by pressure alone, form a metal. Deep inside Jupiter most of the planet's hydrogen is in that state.

5 figures · part 7 on Chemical potential The proton fraction a cold star settles at. The fraction of nucleons that are protons in cold matter in beta equilibrium, where the neutron's chemical potential equals the proton's plus the electron's, against density on logarithmic axes, for free neutrons, protons and electrons with no nuclear forces. Below 1.22·10⁷ g/cm³ the electrons cannot pay the 1.29 MeV difference between a neutron and a proton and the matter is all protons. Above it the fraction collapses, to 0.014 per cent at its lowest near 7.9·10¹¹ g/cm³, and at nuclear density, 2.66·10¹⁴ g/cm³, it is 0.49 per cent. At higher densities it climbs slowly towards one ninth, 11 per cent, which it never reaches. The dashed part lies where real matter is made of nuclei rather than free nucleons.

The protons a star cannot afford

A free neutron decays in fifteen minutes into a proton, an electron and an antineutrino. Inside a neutron star it cannot, and the star is made of neutrons because of it. Beta decay is a reaction like any other, and at equilibrium the neutron's chemical potential must equal the proton's plus the electron's. In a crowded star an electron can only be added at the top of a sea tens of megaelectronvolts deep. So the matter settles where protons are rare: half a per cent of the nucleons at nuclear density, if nucleons were free, and never more than one in nine at any density.

5 figures · part 8 on Chemical potential The gas that has to stop expanding. The thermal expansion coefficient at constant pressure times the temperature, αT, against temperature over the Fermi temperature, on logarithmic axes, for an ideal classical gas and an ideal gas of spin-half fermions at the same density. For the classical gas αT is exactly one at every temperature, so α = 1/T grows without limit as the gas is cooled, which the third law forbids: by a Maxwell relation α is minus the pressure derivative of the entropy per unit volume, and that must vanish at absolute zero. The Fermi gas agrees with the classical one when hot and departs from it near the Fermi temperature; at a tenth of it αT is 0.048, and at a hundredth 0.002, falling as π²/2 times the square of the temperature over the Fermi temperature. Its expansion vanishes as the law requires.

The two laws absolute zero will not allow

The ideal-gas law and Curie's law are the first two equations of state most people meet. The third law of thermodynamics says both must be wrong at low temperature, and it says so without any model of what replaces them. A Maxwell relation turns every derivative of the entropy into something measurable with a ruler or a magnetometer: the thermal expansion, the slope of the magnetisation with temperature. If the entropy stops depending on pressure and field at absolute zero, those must vanish. The classical gas expands as 1/T and Curie's magnetisation climbs as 1/T, and both slopes grow without limit instead.

5 figures · part 8 on Third law

Relativity

Space and time, drawn on the same axes.

Two pushes that nearly cancel. The forces between two equal charges moving side by side at the same speed, measured in the laboratory, in units of the Coulomb force the same two charges exert at rest, against their speed. Electric repulsion grows as γ, because a moving charge's field is stronger across its motion: 2.29 at β = 0.9, 7.1 at 0.99. The magnetic attraction of two parallel currents grows as γβ² and eats it almost entirely: the net push is γ(1 − β²) = 1/γ — 0.436 at 0.9 and 0.141 at 0.99. Measured in the pair's own frame the push is exactly the Coulomb force at every speed; the difference is not a force that exists in one frame and not another but a difference in how fast the two frames' clocks run while the charges drift apart.

The beam that stops pushing itself apart

A beam of electrons is a crowd of like charges, and a crowd of like charges flies apart. A slow beam does, within centimetres. A fast one hardly does at all: at a gigaelectronvolt the same current travels kilometres before its width doubles. The electric repulsion has not weakened — it has grown, by the factor γ. What has grown faster is a magnetic attraction between parallel currents, which cancels all but 1/γ² of the push. Seen from the beam itself there is no magnetism at all, only Coulomb repulsion acting while the beam's clocks run slow.

5 figures · part 7 on Field transformation The orbits of an electron in a travelling wave. The possible motions of an electron in a plasma wave whose phase moves at γₚ = 10 and whose field is 0.2 of the cold wave-breaking field, drawn as its energy against its position in the wave over two wavelengths — the level curves of H = γ − βₚ u − ε cos ψ, which the electron's motion conserves. Inside the separatrix (thick) an electron is trapped: it slides back and forth through the wave, gaining energy while it outruns the wave and losing it while the wave outruns it. The separatrix reaches γ = 99 at its top, near 4γₚ²ε = 80, starting from electrons moving at the wave's own speed. Outside it, electrons that are too slow are overtaken by the wave and those that are fast enough outrun it; neither gains energy on average.

The wave an electron rides to a gigaelectronvolt

A laser pulse fired into a thin plasma pushes its electrons aside and leaves them oscillating behind it, a wave of charge travelling at nearly the speed of light. The field in that wave is a thousand times stronger than any metal accelerator can hold, and an electron caught in it at the right moment is carried along like a surfer, gaining a gigaelectronvolt in a few centimetres. Then it outruns the wave. The distance it can ride, and the energy it can gain, are both set by how nearly the wave keeps pace with it — which is to say, by relativity.

5 figures · part 10 on Relativistic dynamics

Quantum

Where the continuous picture runs out, and what replaces it.

The triangle of collisions that survive. Every collision of a particle ε above a filled Fermi sea with a partner from the sea, at zero temperature: the partner's energy across, one product's energy up, both from the Fermi level, the other product's fixed by energy conservation. Without exclusion every point in the plotted square would be an allowed collision. With it, the partner must come from below the Fermi level, and both products must land above it: the partner no deeper than ε below, the first product above zero, the second product above zero too. What survives is the shaded triangle, whose area is half of ε squared, and the collision rate is proportional to it. Halve the particle's excess energy and the triangle shrinks to a quarter; at the Fermi level itself it vanishes, and a particle there cannot scatter at all.

The collisions the exclusion principle forbids

A copper wire holds one free electron per atom, packed a quarter of a nanometre apart and repelling one another with the full Coulomb force. It seems impossible that an electron could travel any distance through that crowd without colliding. It travels micrometres — thousands of atoms — before another electron deflects it. The collisions are not weak. They are forbidden: to collide, both electrons need empty states to move into, and in a sea filled to the brim almost none exist. The same rule makes cold helium-3 thicken as the square of how cold it gets.

5 figures · part 4 on Exclusion Each wavelength sees from a different height. The weighting functions of 7 infrared channels in a carbon-dioxide band — how much each height contributes to the radiance a satellite measures in that channel — for absorption strengths chosen so that the peaks sit at 3, 8, 14, 20, 27, 35, 43 km. Each is scaled to its own maximum. A channel's peak is where the carbon dioxide above that height amounts to one optical depth: deeper, its emission is absorbed on the way out; higher, there is too little gas to emit. Each function is about 17 km wide at half its peak, the same for every channel, because the absorber's density falls with one scale height, 7 km. The dotted curve is the temperature profile of the standard atmosphere, on its own scale from 180 to 300 K, whose cold tropopause and warm stratosphere the channels between them straddle.

The spectrum that is a thermometer at every height

A satellite looking down at the Earth in the infrared sees, at each wavelength, the glow of whatever layer of air that wavelength escapes from. In the wings of carbon dioxide's great absorption band the air is transparent and the satellite sees the ground; towards the band's centre the gas grows opaque and each wavelength escapes from higher up. A single spectrum is therefore a stack of thermometers at different heights, and weather forecasts are built on reading it. What cannot be read from it is anything much thinner than the ten to twenty kilometres of air each of those thermometers averages over.

5 figures · part 5 on Blackbody

Fluids

Matter that will not hold a shape, and the forces that act in it anyway.

Flow curves that bend back, and one that stops. Shear stress against shear rate, both on logarithmic axes, for volume fractions 0.5, 0.55, 0.565, 0.575, 0.6, from the same model: stress in units of σ, rate in units of σ over the liquid's viscosity. Below φ = 0.569 every curve rises steadily — the suspension thickens but continuously. Above it and below the frictional jamming point 0.58 the curve bends back into an S: over a range of stress, more stress gives less flow, and a suspension driven at a fixed rate must jump between branches. At φ = 0.6 the curve returns to zero rate at 2.47 σ*: pushed that hard, the suspension stops flowing altogether and holds the stress like a solid.

The suspension that seizes when pushed hard

Cornflour stirred into half its volume of water runs off a spoon like cream, and a fist driven into it bounces off as if it had hit a floor. The particles have not changed and neither has the water. What changes, above a threshold stress, is the kind of contact between neighbouring grains: lubricated, they slide past one another and the suspension can pack to 64 per cent before it locks; pressed into frictional contact, they lock at 58. A suspension sitting between those two numbers is a liquid when handled gently and a solid when handled hard.

5 figures · part 6 on Rheology The deepest water reads warmer than the water above it. A column of seawater 10.9 km deep whose potential temperature — the temperature each parcel would have if brought to the surface without gaining or losing heat — falls from 20 °C at the top to 1 °C in the deep, and the temperature a thermometer lowered into it would read. The two agree near the surface and part company with depth: the thermometer reads a minimum of 1.38 °C near 3.9 km and then rises to 2.35 °C at the bottom, although the water there is the same water, with the same potential temperature, 1.00 °C, as the water two kilometres higher. The warming is compression alone; no heat reaches the deep trench from anywhere.

The water that warms on the way down

Lower a thermometer into the Mariana Trench and it reads colder and colder for four kilometres and then starts to warm, reaching about two and a half degrees at the bottom, eleven kilometres down. No heat is coming up from the sea floor to do it. The water at the bottom is the same water as the water two kilometres higher, carried down and squeezed, and squeezing warms it. In fresh water near four degrees the same squeezing does nothing at all, and below four degrees it cools — so a parcel of cold lake water pushed deep enough keeps sinking on its own.

5 figures · part 7 on Hydrostatics Chains counted, and then blobs. The osmotic pressure of a polymer solution in a good solvent against concentration, on logarithmic axes, for chains of 1,000, 10,000, 100,000 segments. Dilute, each chain is one particle and the pressure is van 't Hoff's, proportional to the number of chains: a line of slope one, lower for longer chains by the ratio of their lengths. Past the overlap concentration of each, marked, the coils interpenetrate and the curves bend up onto a single line of slope 2.31 that does not depend on chain length at all. The overlap concentration falls as the chains lengthen, by a factor of 5.8 for each tenfold increase in length, which is why the longest chains leave the counting of molecules first.

The pressure that stops counting molecules

Van 't Hoff's law counts dissolved particles, and for a dilute polymer each chain is one particle, however many thousand segments it has. That is how osmometers weigh polymers. Concentrate the solution until the coils overlap and the count changes. The pressure stops depending on how long the chains are and grows as the 2.3 power of the concentration, the same for chains a thousand segments long and a hundred thousand. The unit being counted is no longer a molecule. It is a stretch of chain as long as the mesh of its neighbours allows, and it has no chemical identity at all.

5 figures · part 7 on Osmosis The pull of a meniscus against the stiffness of a wall. For two neighbouring lines of a wet pattern leaning towards each other, the net Laplace pressure pulling them together (heavy curve) and the bending stiffness pushing them back (straight lines), against the lean as a fraction of the half-gap. The pull grows faster than linearly, because narrowing a gap raises its suction, and it diverges as the gap closes. The stiffness is a straight line whose slope falls as the fourth power of the line's height; the lines drawn are for 0.8 times, 1 times, 1.25 times the critical height. At 0.8 of the critical height the straight state is stable and an unstable balance lies at a lean of 0.77 of the half-gap, a barrier the lines must be pushed over; at the critical height the two start with the same slope and the straight state is marginal; at 1.25 times the straight state is unstable and the pair collapses.

The walls a rinse pulls together

Every result about capillary rise assumes the walls hold still. Make them thin enough and they do not. The water between two walls is below atmospheric pressure, so it pulls them together, and as the gap narrows the suction grows. Beyond a critical height or length the walls cannot push back and they snap shut. It is why wet hair clumps, why a paintbrush comes out of water as a point, and why a chip factory cannot rinse lines of resist taller than about three times their width without laying them flat.

5 figures · part 7 on Capillarity

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